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Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes.

ABSTRACT: A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki-Miyaura cross-coupling applications are also presented.

SUBMITTER: Kondoh A 

PROVIDER: S-EPMC2825324 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes.

Kondoh Azusa A   Jamison Timothy F TF  

Chemical communications (Cambridge, England) 20100105 6

A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki-Miyaura cross-coupling applications are also presented. ...[more]

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