Unknown

Dataset Information

0

Examination of the Dynamic Covalent Chemistry of [2 + 3]-Imine Cages.


ABSTRACT: The synthesis of shape-persistent organic cage compounds by the formation of imine bonds opens the possibility to realize cages of different sizes, geometries, topologies, and functions. It is generally assumed that the imine bond is rather chemically labile allowing a self-correction mechanism until thermodynamic equilibrium is reached, which is often the case if a cage is formed. However, there are some contradictory experimental data to this assumption. To get a deeper insight into the imine bond dynamics of covalent organic cages, we studied the formation and exchange of both dialdehydes and triamines of two different [2 + 3] imine cages with the aid of a deuterated dialdehyde molecular building block.

SUBMITTER: Schick THG 

PROVIDER: S-EPMC7659045 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature

altmetric image

Publications

Examination of the Dynamic Covalent Chemistry of [2 + 3]-Imine Cages.

Schick Tobias H G THG   Rominger Frank F   Mastalerz Michael M  

The Journal of organic chemistry 20201009 21


The synthesis of shape-persistent organic cage compounds by the formation of imine bonds opens the possibility to realize cages of different sizes, geometries, topologies, and functions. It is generally assumed that the imine bond is rather chemically labile allowing a self-correction mechanism until thermodynamic equilibrium is reached, which is often the case if a cage is formed. However, there are some contradictory experimental data to this assumption. To get a deeper insight into the imine  ...[more]

Similar Datasets

| S-EPMC6996569 | biostudies-literature
| S-EPMC6470955 | biostudies-literature
| S-EPMC9531658 | biostudies-literature
| S-EPMC8905640 | biostudies-literature
| S-EPMC9080712 | biostudies-literature
| S-EPMC8276630 | biostudies-literature
| S-EPMC6251970 | biostudies-literature
| S-EPMC8163447 | biostudies-literature
| S-EPMC8565364 | biostudies-literature
| S-EPMC10975865 | biostudies-literature