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Ruthenium-Catalyzed trans-Hydroalkynylation and trans-Chloroalkynylation of Internal Alkynes.


ABSTRACT: [Cp*RuCl]4 catalyzes the addition of iPr3SiC?CX (X = H, Cl) across internal alkynes with formation of 1,3-enyne or 1-chloro-1,3-enyne derivatives, respectively; the reaction follows an unorthodox trans-addition mode. The well-balanced affinities of the different reaction partners to the ruthenium catalyst ensure that crossed addition prevails over homodimerization of the individual components, as can be deduced from spectroscopic and crystallographic data of various intermediates; this includes a dinuclear complex in which an internal alkyne bridges two [Cp*RuCl] fragments.

SUBMITTER: Barsu N 

PROVIDER: S-EPMC7660751 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature

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Ruthenium-Catalyzed <i>trans</i>-Hydroalkynylation and <i>trans</i>-Chloroalkynylation of Internal Alkynes.

Barsu Nagaraju N   Leutzsch Markus M   Fürstner Alois A  

Journal of the American Chemical Society 20201023 44


[Cp*RuCl]<sub>4</sub> catalyzes the addition of <i>i</i>Pr<sub>3</sub>SiC≡CX (X = H, Cl) across internal alkynes with formation of 1,3-enyne or 1-chloro-1,3-enyne derivatives, respectively; the reaction follows an unorthodox <i>trans</i>-addition mode. The well-balanced affinities of the different reaction partners to the ruthenium catalyst ensure that crossed addition prevails over homodimerization of the individual components, as can be deduced from spectroscopic and crystallographic data of v  ...[more]

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