Ontology highlight
ABSTRACT:
SUBMITTER: Wang Y
PROVIDER: S-EPMC7679077 | biostudies-literature | 2018 Jun
REPOSITORIES: biostudies-literature
Wang Yuzhong Y Xie Yaoming Y Wei Pingrong P Blair Soshawn A SA Cui Dongtao D Johnson Michael K MK Schaefer Henry F HF Robinson Gregory H GH
Angewandte Chemie (International ed. in English) 20180522 26
Whereas low-temperature (-78 °C) reaction of the lithium dithiolene radical 1<sup>.</sup> with boron bromide gives the dibromoboron dithiolene radical 2<sup>.</sup> , the parallel reaction of 1<sup>.</sup> with (C<sub>6</sub> H<sub>11</sub> )<sub>2</sub> BCl (0 °C) affords the dicyclohexylboron dithiolene radical 3<sup>.</sup> . Radicals 2<sup>.</sup> and 3<sup>.</sup> were characterized by single-crystal X-ray diffraction, UV/Vis, and EPR spectroscopy. The nature of these radicals was also prob ...[more]