Unknown

Dataset Information

0

A Stable Naked Dithiolene Radical Anion and Synergic THF Ring-Opening.


ABSTRACT: Reaction of the lithium dithiolene radical 2 with the imidazolium salt [{(Me)CN(i-Pr)}2CH]+[Cl]- (in a 1:1 molar ratio) gives the first stable naked anionic dithiolene radical 3, which, when coupled with hexasulfide, [{(Me)CN(i-Pr)}2CH]+2[S6]2- (4), and N-heterocyclic silylene 5, unexpectedly results in synergic THF ring-opening via a radical mechanism.

SUBMITTER: Wang Y 

PROVIDER: S-EPMC7682752 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC5551979 | biostudies-literature
| S-EPMC8276880 | biostudies-literature
| S-EPMC7679077 | biostudies-literature
| S-EPMC8499027 | biostudies-literature
| S-EPMC11345820 | biostudies-literature
| S-EPMC10666543 | biostudies-literature
| S-EPMC6941592 | biostudies-literature
| S-EPMC10539349 | biostudies-literature
| S-EPMC6240899 | biostudies-other
| S-EPMC9710740 | biostudies-literature