Persistent Organic High-Spin Trinitrenes.
Ontology highlight
ABSTRACT:
SUBMITTER: Mendez-Vega E
PROVIDER: S-EPMC7687127 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
Publications
Persistent Organic High-Spin Trinitrenes.
Mendez-Vega Enrique E Mieres-Perez Joel J Chapyshev Sergei V SV Sander Wolfram W
Angewandte Chemie (International ed. in English) 20190730 37
The septet ground state trinitrenes 1,3,5-trichloro-2,4,6-trinitrenobenzene and 1,3,5-tribromo-2,4,6-trinitrenobenzene were isolated in inert (Ar, Ne, and Xe) as well as reactive matrices (H<sub>2</sub> , O<sub>2</sub> , and H<sub>2</sub> O) at cryogenic temperatures. These trinitrenes were obtained in high yields by UV photolysis of the corresponding triazides and characterized by IR and UV/Vis spectroscopy. The trinitrenes, despite bearing six unpaired electrons, are remarkably unreactive towa ...[more]
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