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A Phosphine Functionalized ?-Diketimine Ligand for the Synthesis of Manifold Metal Complexes.


ABSTRACT: A bis(diphenyl)-phosphine functionalized ?-diketimine (PNac-H) was synthesized as a flexible ligand for transition metal complexes. The newly designed ligand features symmetrically placed phosphine moieties around a ?-diketimine unit, forming a PNNP-type pocket. Due to the hard and soft donor atoms (N vs. P) the ligand can stabilize various coordination polyhedra. A complete series ranging from coordination numbers 2 to 6 was realized. Linear, trigonal planar, square planar, tetrahedral, square pyramidal, and octahedral coordination arrangements containing the PNac-ligand around the metal center were observed by using suitable metal sources. Hereby, PNac-H or its anion PNac- acts as mono-, bi- and tetradendate ligand. Such a broad flexibility is unusual for a rigid tetradentate system. The structural motifs were realized by treatment of PNac-H with a series of late transition metal precursors, for example, silver, gold, nickel, copper, platinum, and rhodium. The new complexes have been fully characterized by single crystal X-ray diffraction, NMR, IR, UV/Vis spectroscopy, mass spectrometry as well as elemental analysis. Additionally, selected complexes were investigated regarding their photophysical properties. Thus, PNac-H proved to be an ideal ligand platform for the selective coordination and stabilization of various metal ions in diverse polyhedra and oxidation states.

SUBMITTER: Zovko C 

PROVIDER: S-EPMC7693294 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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A Phosphine Functionalized β-Diketimine Ligand for the Synthesis of Manifold Metal Complexes.

Zovko Christina C   Bestgen Sebastian S   Schoo Christoph C   Görner Anne A   Goicoechea Jose M JM   Roesky Peter W PW  

Chemistry (Weinheim an der Bergstrasse, Germany) 20200831 58


A bis(diphenyl)-phosphine functionalized β-diketimine (PNac-H) was synthesized as a flexible ligand for transition metal complexes. The newly designed ligand features symmetrically placed phosphine moieties around a β-diketimine unit, forming a PNNP-type pocket. Due to the hard and soft donor atoms (N vs. P) the ligand can stabilize various coordination polyhedra. A complete series ranging from coordination numbers 2 to 6 was realized. Linear, trigonal planar, square planar, tetrahedral, square  ...[more]

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