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Complexes of Dichlorogermylene with Phosphine/Sulfoxide-Supported Carbone as Ligand.

ABSTRACT: Due to their remarkable electronic features, recent years have witnessed the emergence of carbones L2C, which consist in two donating L ligands coordinating a central carbon atom bearing two lone pairs. In this context, the phosphine/sulfoxide-supported carbone 4 exhibits a strong nucleophilic character, and here, we describe its ability to coordinate dichlorogermylene. Two original stable coordination complexes were obtained and fully characterized in solution and in the solid state by NMR spectroscopy and X-ray diffraction analysis, respectively. At 60 °C, in the presence of 4, the Ge(II)-complex 5 undergoes a slow isomerization that transforms the bis-ylide ligand into an yldiide.

SUBMITTER: Authesserre U

PROVIDER: S-EPMC8037485 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature

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Complexes of Dichlorogermylene with Phosphine/Sulfoxide-Supported Carbone as Ligand.

Authesserre Ugo U Hameury Sophie S Dajnak Aymeric A Saffon-Merceron Nathalie N Baceiredo Antoine A Madec David D Maerten Eddy E

Molecules (Basel, Switzerland) 20210401 7

Due to their remarkable electronic features, recent years have witnessed the emergence of carbones L2C, which consist in two donating L ligands coordinating a central carbon atom bearing two lone pairs. In this context, the phosphine/sulfoxide-supported carbone 4 exhibits a strong nucleophilic character, and here, we describe its ability to coordinate dichlorogermylene. Two original stable coordination complexes were obtained and fully characterized in solution and in the solid ...[more]

PMID: 33916075

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