Dataset Information

Visual Simultaneous Detection and Real-Time Monitoring of Cadmium Ions Based on Conjugated Polydiacetylenes.

ABSTRACT: We prepared the monomer PCDA-HP composed of 5-hydroxy-N ¹,N ³-bis(pyridin-2-ylmethyl)isophthalamide (HP) as a cadmium ion tweezer and then polymerized them to form a polydiacetylene (PDA)-based sensor (PDA-HP), which displayed selective and sensitive colorimetric and fluorometric change upon addition of a cadmium ion (Cd²⁺) at both pH 7.4 and 6.8. The PDA-HP polymer was highly selective for Cd²⁺ over other metal ions with colorimetric change. In addition, the PDA-HP chemosensor also showed a red fluorescence change in the presence of Cd²⁺ at both pH 7.4 and 6.8. Naked-eye detection of Cd²⁺ was accomplished in an aqueous solution through a PDA-based sensor system. Finally, the lowest energy structure of an HP chelator was obtained by the crystal structure and density functional theory (DFT) calculations.

SUBMITTER: Pham TC

PROVIDER: S-EPMC7726929 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

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Visual Simultaneous Detection and Real-Time Monitoring of Cadmium Ions Based on Conjugated Polydiacetylenes.

Pham Thanh Chung TC Lee Seongman S Kim Dongwon D Jung Ok-Sang OS Lee Myung Won MW Lee Songyi S

ACS omega 20201123 48

We prepared the monomer PCDA-HP composed of 5-hydroxy-N 1,N 3-bis(pyridin-2-ylmethyl)isophthalamide (HP) as a cadmium ion tweezer and then polymerized them to form a polydiacetylene (PDA)-based sensor (PDA-HP), which displayed selective and sensitive colorimetric and fluorometric change upon addition of a cadmium ion (Cd2+) at both pH 7.4 and 6.8. The PDA-HP polymer was highly selective for Cd2+ over other meta ...[more]

PMID: 33324835

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Project description:A thirst for the development of a simple fluorescence probe for enhanced sensing application has been achieved by synthesizing a stupendous thiophene-appended benzothiazole-conjugated compound L2. The synthesized compound L2 was characterized using nuclear magnetic resonance and mass spectrometry techniques. Furthermore, a photophysical property of L1 and L2 reveals the enhanced emission spectrum of L2 because of a restricted spin-orbital coupling as a result of increased conjugation compared to the ligand L1. Therefore, comparative studies were undertaken for L1 and L2. Henceforth, L2 was deployed for the ratiometric detection of Cd2+ ions in THF:water and L1 for the detection of Cu2+ ions in THF medium. The chemosensor L2 shows an outstanding water tolerance up to 60% and is stable between pH 2 and 7. This level of water tolerance and stability make L2 a suitable probe for analyzing real-time and biological samples. While the cadmium ion was added to L2, there was a significant red shift in emission from 496 to 549 nm, which indicates the controlled ICT due to complex formation. The metal-ligand complexation was also confirmed by noticing a decreased band gap of metal complex compared to the ligand as calculated using Tauc's plot with solid-phase UV data. The stoichiometric ratio was obtained by Job's plot that exhibited a 1:1 ratio of L2 and Cd2+ ions, and the limit of detection (LOD) was found to be 2.25 nM by the photoluminescence spectroscopic technique. The fluorescence lifetime of both L2 and L2-Cd2+ was found to be 58.3 ps and 0.147 ns, respectively. Alongside, the colorimetric-assisted ratiometric detection of Cu2+ by L1 with 1:2 stoichiometric ratio having an LOD of 1.06 × 10-7 M was also performed. Furthermore, the practical applicability of the probe L2 in sensing cadmium was tested in sewage water and vegetable extract; the recovery was approximately 98 and 99%, respectively. The experimental data were supported by theoretical investigation of structures of L1, L2, L1-Cu2+ , and L2-Cd2+ , complex formation, charge transfer mechanism, and band gap measurements done by quantum chemical density functional theory calculations.

Dataset Information

Visual Simultaneous Detection and Real-Time Monitoring of Cadmium Ions Based on Conjugated Polydiacetylenes.

Publications

Visual Simultaneous Detection and Real-Time Monitoring of Cadmium Ions Based on Conjugated Polydiacetylenes.

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