Ontology highlight
ABSTRACT:
SUBMITTER: Kundu G
PROVIDER: S-EPMC7756449 | biostudies-literature | 2020 Dec
REPOSITORIES: biostudies-literature
Kundu Gourab G Sperger Theresa T Rissanen Kari K Schoenebeck Franziska F
Angewandte Chemie (International ed. in English) 20200928 49
We report a new air-stable Pd<sup>I</sup> dimer, [Pd(μ-I)(PCy<sub>2</sub> <sup>t</sup> Bu)]<sub>2</sub> , which triggers E-selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C-C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C-Br, C-OTf/OFs, and C-Cl bonds in poly(pseudo)halogenated arenes, displa ...[more]