Ontology highlight
ABSTRACT:
SUBMITTER: Winter M
PROVIDER: S-EPMC7756667 | biostudies-literature | 2020 Dec
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20201027 68
Trifluoromethylation of [AuF<sub>3</sub> (SIMes)] with the Ruppert-Prakash reagent TMSCF<sub>3</sub> in the presence of CsF yields the product series [Au(CF<sub>3</sub> )<sub>x</sub> F<sub>3-x</sub> (SIMes)] (x=1-3). The degree of trifluoromethylation is solvent dependent and the ratio of the species can be controlled by varying the stoichiometry of the reaction, as evidenced from the <sup>19</sup> F NMR spectra of the corresponding reaction mixtures. The molecular structures in the solid state ...[more]