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Fabrication of Highly Porous Polymeric Nanocomposite for the Removal of Radioactive U(VI) and Eu(III) Ions from Aqueous Solution.

ABSTRACT: In the present study, a polymeric nanocomposite, CoFe₂O₄@DHBF, was fabricated using 2,4 dihydroxybenzaldehyde and formaldehyde in basic medium with CoFe₂O₄ nanoparticles. The fabricated nanocomposite was characterized using FTIR, TGA, XRD, SEM, TEM, and XPS analyses. The analytical results revealed that the magnetic nanocomposite was fabricated successfully with high surface area 370.24 m²/g. The fabricated CoFe₂O₄@DHBF was used as an efficient adsorbent for the adsorption of U(VI) and Eu(III) ions from contaminated water. pH, initial concentration, adsorption time, and the temperature of the contaminated water solution affecting the adsorption ability of the nanocomposites were studied. The batch adsorption results exposed that the adsorption capacity for the removal of U(VI) and Eu(III) was found to be 237.5 and 225.5 mg/g. The adsorption kinetics support that both the metal ions follow second order adsorption kinetics. The adsorption isotherm well fits with the Langmuir adsorption isotherm and the correlation coefficient (R²) values were found to be 0.9920 and 0.9913 for the adsorption of U(VI) and Eu(III), respectively. It was noticed that the fabricated nanocomposites show excellent regeneration ability and about 220.1 and 211.3 mg/g adsorption capacity remains with U(VI) and Eu(III) under optimum conditions.

SUBMITTER: Ahamad T

PROVIDER: S-EPMC7763886 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

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Fabrication of Highly Porous Polymeric Nanocomposite for the Removal of Radioactive U(VI) and Eu(III) Ions from Aqueous Solution.

Ahamad Tansir T Naushad Mu M Ubaidullah Mohd M Alshehri Saad S

Polymers 20201209 12

In the present study, a polymeric nanocomposite, CoFe2O4@DHBF, was fabricated using 2,4 dihydroxybenzaldehyde and formaldehyde in basic medium with CoFe2O4 nanoparticles. The fabricated nanocomposite was characterized using FTIR, TGA, XRD, SEM, TEM, and XPS analyses. The analytical results revealed that the magnetic nanocomposite was fabricated successfully with high surface area 370.24 m2/g. The fabricated CoFe2O4@DHBF ...[more]

PMID: 33316959

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Project description:Heavy metal ions in water refer to significant risks to the biological system due to their high toxicity. Therefore, the decontamination of water polluted by heavy metal ions attracts significant interest of researchers. Adsorption by nanomaterials has been a widely used technique for removing heavy metal ions from water. Chitosan was extracted from shrimp shellfish and mixed with laboratory-prepared AgNPs/GO in the ratio of 3 : 1. A series of tests evaluates the best condition of pH, amount of adsorbent, retention time, stirring speed, temp, and initial concentration. The research was conducted under various conditions. Langmuir, Freundlich, Tempkin, and Dubinin-Radushkevich isotherms were also tested. Also, the column adsorption experiment was carried out on industrial wastewater at different flow rates and column bed heights. The optimal values of the contact time, pH, and adsorbent dose of Cr(vi) were found to be 80 min, 4, and 0.1 g 100 mL-1, respectively, at room temperature (30 °C), agitation at 150 rpm, and initial concentration of 50 ppm. On the other hand, the optimal value of contact time, pH, and adsorbent dose of Fe(iii) were found to be 30 min, 6, and 0.02 g 100 mL-1, respectively, at room temp (30 °C) with a stirring speed of 250 rpm and an initial concentration of 40 ppm. For Cr(vi) and Fe(iii), equilibrium studies show that the data fit the Freundlich isotherm well (correlation coefficient, R 2 = 0.98) (III). A link between the pseudo-second order active model and data fitting the pseudo-first order active models were made. Within the intraparticle diffusion model, there are four stages that the mechanism must go through before it is at equilibrium. The adsorbent was tested in an industrial adsorbent column. This test proves that the nanocomposite's adsorption capacity can be restored by washing it with 0.1 M HCl, as shown by the periodicity test. After four cycles, the amount of Cr(vi) adsorbed on AgNPs/GO/chitosan was just 20%, which is insufficient for further adsorption experiments. Cr(vi) removal rates (%R) decreased slightly.

Dataset Information

Fabrication of Highly Porous Polymeric Nanocomposite for the Removal of Radioactive U(VI) and Eu(III) Ions from Aqueous Solution.

Publications

Fabrication of Highly Porous Polymeric Nanocomposite for the Removal of Radioactive U(VI) and Eu(III) Ions from Aqueous Solution.

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