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Ultrathin and Flexible CNTs/MXene/Cellulose Nanofibrils Composite Paper for Electromagnetic Interference Shielding.

ABSTRACT: As the rapid development of portable and wearable devices, different electromagnetic interference (EMI) shielding materials with high efficiency have been desired to eliminate the resulting radiation pollution. However, limited EMI shielding materials are successfully used in practical applications, due to the heavy thickness and absence of sufficient strength or flexibility. Herein, an ultrathin and flexible carbon nanotubes/MXene/cellulose nanofibrils composite paper with gradient and sandwich structure is constructed for EMI shielding application via a facile alternating vacuum-assisted filtration process. The composite paper exhibits outstanding mechanical properties with a tensile strength of 97.9 ± 5.0 MPa and a fracture strain of 4.6 ± 0.2%. Particularly, the paper shows a high electrical conductivity of 2506.6 S m^-1 and EMI shielding effectiveness (EMI SE) of 38.4 dB due to the sandwich structure in improving EMI SE, and the gradient structure on regulating the contributions from reflection and absorption. This strategy is of great significance in fabricating ultrathin and flexible composite paper for highly efficient EMI shielding performance and in broadening the practical applications of MXene-based composite materials.

SUBMITTER: Cao W

PROVIDER: S-EPMC7770921 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Porous and Ultra-Flexible Crosslinked MXene/Polyimide Composites for Multifunctional Electromagnetic Interference Shielding.

Project description:Lightweight, ultra-flexible, and robust crosslinked transition metal carbide (Ti3C2 MXene) coated polyimide (PI) (C-MXene@PI) porous composites are manufactured via a scalable dip-coating followed by chemical crosslinking approach. In addition to the hydrophobicity, anti-oxidation and extreme-temperature stability, efficient utilization of the intrinsic conductivity of MXene, the interfacial polarization between MXene and PI, and the micrometer-sized pores of the composite foams are achieved. Consequently, the composites show a satisfactory X-band electromagnetic interference (EMI) shielding effectiveness of 22.5 to 62.5 dB at a density of 28.7 to 48.7 mg cm-3, leading to an excellent surface-specific SE of 21,317 dB cm2 g-1. Moreover, the composite foams exhibit excellent electrothermal performance as flexible heaters in terms of a prominent, rapid reproducible, and stable electrothermal effect at low voltages and superior heat performance and more uniform heat distribution compared with the commercial heaters composed of alloy plates. Furthermore, the composite foams are well attached on a human body to check their electromechanical sensing performance, demonstrating the sensitive and reliable detection of human motions as wearable sensors. The excellent EMI shielding performance and multifunctionalities, along with the facile and easy-to-scalable manufacturing techniques, imply promising perspectives of the porous C-MXene@PI composites in next-generation flexible electronics, aerospace, and smart devices.

| S-EPMC8828842 | biostudies-literature

Ultrathin, Lightweight, and Flexible CNT Buckypaper Enhanced Using MXenes for Electromagnetic Interference Shielding.

Project description:Lightweight, flexibility, and low thickness are urgent requirements for next-generation high-performance electromagnetic interference (EMI) shielding materials for catering to the demand for smart and wearable electronic devices. Although several efforts have focused on constructing porous and flexible conductive films or aerogels, few studies have achieved a balance in terms of density, thickness, flexibility, and EMI shielding effectiveness (SE). Herein, an ultrathin, lightweight, and flexible carbon nanotube (CNT) buckypaper enhanced using MXenes (Ti3C2Tx) for high-performance EMI shielding is synthesized through a facile electrophoretic deposition process. The obtained Ti3C2Tx@CNT hybrid buckypaper exhibits an outstanding EMI SE of 60.5 dB in the X-band at 100 μm. The hybrid buckypaper with an MXene content of 49.4 wt% exhibits an EMI SE of 50.4 dB in the X-band with a thickness of only 15 μm, which is 105% higher than that of pristine CNT buckypaper. Furthermore, an average specific SE value of 5.7 × 104 dB cm2 g-1 is exhibited in the 5-μm hybrid buckypaper. Thus, this assembly process proves promising for the construction of ultrathin, flexible, and high-performance EMI shielding films for application in electronic devices and wireless communications.

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Bridging sheet size controls densification of MXene films for robust electromagnetic interference shielding.

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| S-EPMC9464893 | biostudies-literature

Improved Mechanical Strength of Dicatechol Crosslinked MXene Films for Electromagnetic Interference Shielding Performance.

Project description:Pristine MXene films express outstanding excellent electromagnetic interference (EMI) shielding properties. Nevertheless, the poor mechanical properties (weak and brittle nature) and easy oxidation of MXene films hinder their practical applications. This study demonstrates a facile strategy for simultaneously improving the mechanical flexibility and the EMI shielding of MXene films. In this study, dicatechol-6 (DC), a mussel-inspired molecule, was successfully synthesized in which DC as mortars was crosslinked with MXene nanosheets (MX) as bricks to create the brick-mortar structure of the MX@DC film. The resulting MX@DC-2 film has a toughness of 40.02 kJ·m-3 and Young's modulus of 6.2 GPa, which are improvements of 513% and 849%, respectively, compared to those of the bare MXene films. The coating of electrically insulating DC significantly reduced the in-plane electrical conductivity from 6491 S·cm-1 for the bare MXene film to 2820 S·cm-1 for the MX@DC-5 film. However, the EMI shielding effectiveness (SE) of the MX@DC-5 film reached 66.2 dB, which is noticeably greater than that of the bare MX film (61.5 dB). The enhancement in EMI SE resulted from the highly ordered alignment of the MXene nanosheets. The synergistic concurrent enhancement in the strength and EMI SE of the DC-coated MXene film can facilitate the utilization of the MXene film in reliable, practical applications.

| S-EPMC10005341 | biostudies-literature

Highly Bendable and Durable Waterproof Paper for Ultra-High Electromagnetic Interference Shielding.

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| S-EPMC6780577 | biostudies-literature

Direct Ink Writing of Highly Conductive MXene Frames for Tunable Electromagnetic Interference Shielding and Electromagnetic Wave-Induced Thermochromism.

Project description:Highlights3D printing of MXene frames with tunable electromagnetic interference shielding efficiency is demonstrated. Highly conductive MXene frames are reinforced by cross-linking with aluminum ions. Electromagnetic wave is visualized by electromagnetic-thermochromic MXene patterns. The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference (EMI) shielding materials to assure the normal operation of their closely assembled components. However, the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency. Herein, we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications. The as-printed frames are reinforced by immersing in AlCl3/HCl solution to remove the electrically insulating AlOOH nanoparticles, as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions. After freeze-drying, the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25-80 dB with the highest electrical conductivity of 5323 S m-1. Furthermore, an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern, and its color can be changed from blue to red under the high-intensity electromagnetic irradiation. This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves.

| S-EPMC8219826 | biostudies-literature

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