Lanthanide Luminescence Enhancement of Core-Shell Magnetite-SiO₂ Nanoparticles Covered with Chain-Structured Helical Eu/Tb Complexes.

ABSTRACT: Oligomeric-brush chains of helical lanthanide (Ln) complexes retain their structural and luminescent behavior after coating onto magnetic nanoparticles (MNPs) consisting of Fe₃O₄ covered with silicate. It is one of the type of bifunctional NPs exhibiting luminescence of Ln and superparamagnetism of Fe₃O₄. In comparison to a simple monolayer of complexes adsorbed on a modified surface, a layer made of luminescent chains allowed us to obtain a more intensive red/green luminescence originating from Eu³⁺/Tb³⁺ ions, and at the same time, no visible increase in particle size (compared to Fe₃O₄@silica particles) was observed. The luminescent properties of the Tb³⁺ complex were altered by MNPs; the decrease of the luminescence was not as large as expected, the excitation spectrum changed significantly, and the average luminescence lifetime was much longer at room temperature. Surprisingly, this phenomenon was not observed at 77 K and also did not occur for the Eu³⁺ complexes. The possibility to stack building blocks in a chain using complexes of different lanthanide ions can be used to design novel multifunctional nanosystems.

SUBMITTER: Goderski S 

PROVIDER: S-EPMC7774089 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature