Unknown

Dataset Information

0

Renewable Cyclopentanol From Catalytic Hydrogenation-Rearrangement of Biomass Furfural Over Ruthenium-Molybdenum Bimetallic Catalysts


ABSTRACT: Biomass furfural-like compounds are chemicals that cannot be extracted from fossil materials, through which a large number of fine chemicals and fuel additives can be opened up, but one big efficiency problem during the transformation is the accumulation of oligomers. Here, we propose a novel and efficient Ru-Mo bimetallic catalyst for selective hydrogenation-rearrangement of furfural-like compounds. The result showed that an unprecedented rearrangement product selectivity of 89.1% to cyclopentanol was achieved under an optimized reaction condition over a 1%Ru?2.5%Mo/CNT catalyst reduced at 600°C. Subsequent characterization suggested that the catalyst presented with weak acidity and strong hydrogenation activity for the reaction, which not only ensures the smooth hydrogenation-rearrangement reaction but also inhibits the accumulation of furan polymers. These findings provide a convenient strategy to tune the catalytic performance of Mo-based catalysts by controlling the reduction and carburization conditions, which appear to be versatile for the rearrangement of furans and similar compounds.

SUBMITTER: Meng S 

PROVIDER: S-EPMC7775491 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC8658772 | biostudies-literature
| S-EPMC3501696 | biostudies-literature
| S-EPMC5719468 | biostudies-literature
| S-EPMC5453137 | biostudies-other
| S-EPMC9306539 | biostudies-literature
| S-EPMC9055482 | biostudies-literature
| S-EPMC7296157 | biostudies-literature
| S-EPMC9355964 | biostudies-literature
| S-EPMC6644560 | biostudies-literature
| S-EPMC10821942 | biostudies-literature