Ontology highlight
ABSTRACT:
SUBMITTER: Kim S
PROVIDER: S-EPMC7783729 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
Organic letters 20201223 1
This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4'-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scal ...[more]