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Multifunctional Charge-Transfer Single Crystals through Supramolecular Assembly.

ABSTRACT: Centimeter-sized segregated stacking TTF-C60 single crystals are crystallized by a mass-transport approach combined with solvent-vapor evaporation for the first time. The intermolecular charge-transfer interaction in the long-range ordered superstructure enables the crystals to demonstrate external stimuli-controlled multifunctionalities and angle/electrical-potential-dependent luminescence.

SUBMITTER: Xu B 

PROVIDER: S-EPMC7798091 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Multifunctional Charge-Transfer Single Crystals through Supramolecular Assembly.

Xu Beibei B   Luo Zhipu Z   Wilson Andrew J AJ   Chen Ke K   Gao Wenxiu W   Yuan Guoliang G   Chopra Harsh Deep HD   Chen Xing X   Willets Katherine A KA   Dauter Zbigniew Z   Ren Shenqiang S  

Advanced materials (Deerfield Beach, Fla.) 20160504 26

Centimeter-sized segregated stacking TTF-C60 single crystals are crystallized by a mass-transport approach combined with solvent-vapor evaporation for the first time. The intermolecular charge-transfer interaction in the long-range ordered superstructure enables the crystals to demonstrate external stimuli-controlled multifunctionalities and angle/electrical-potential-dependent luminescence. ...[more]

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