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Reusable Hyperbranched Polyethylenimine-Functionalized Ethyl Cellulose Film for the Removal of Phosphate with Easy Separation.


ABSTRACT: The design of a reusable film adsorbent with easy solid-liquid separation for the removal of phosphate is necessary and significant but remains hugely challenging. Herein, the hyperbranched polyethylenimine-functionalized ethyl cellulose (HPEI-EC) film was successfully synthesized by a one-step solution-casting method. The structure and elemental composition of the HPEI-EC film were characterized by Fourier transform-infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. The phosphate adsorption capacity of the HPEI-EC film was 15.53 mg g-1, which is 12 times higher than that of EC. Significantly, the elongation at break of the HPEI-EC film was 13.43%, which is higher than that of the EC film (8.9%), and the HPEI-EC film had a considerable tensile strength of 13.21 MPa. Such good mechanical properties of the HPEI-EC film bring about the advantage of the saturated HPEI-EC film, allowing it to be easily taken out using a pair of tweezers, which significantly reduces the operation time and saves the cost in the application process. Furthermore, the HPEI-EC film possessed good reusability, and 71.6% of the original adsorption capacity of phosphate was retained even after five cycles. Moreover, the electrostatic interaction between protonated the amine group (-NH3 +) and the phosphate ion (PO4 3-) is mainly responsible for the adsorption process. This study presents a low-cost and reusable film adsorbent for the effective removal of phosphate from water and provides an easy solid-liquid separation method for use in the adsorption field.

SUBMITTER: Zong E 

PROVIDER: S-EPMC7807744 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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Reusable Hyperbranched Polyethylenimine-Functionalized Ethyl Cellulose Film for the Removal of Phosphate with Easy Separation.

Zong Enmin E   Guo Binlu B   Yang Jiayao J   Shi Chao C   Jiang Shengtao S   Ma Zhongqing Z   Liu Xiaohuan X  

ACS omega 20201224 1


The design of a reusable film adsorbent with easy solid-liquid separation for the removal of phosphate is necessary and significant but remains hugely challenging. Herein, the hyperbranched polyethylenimine-functionalized ethyl cellulose (HPEI-EC) film was successfully synthesized by a one-step solution-casting method. The structure and elemental composition of the HPEI-EC film were characterized by Fourier transform-infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning electron  ...[more]

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