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Syringa vulgaris leaves powder a novel low-cost adsorbent for methylene blue removal: isotherms, kinetics, thermodynamic and optimization by Taguchi method.

ABSTRACT: In this study, the potential of a new low-cost adsorbent, Syringa vulgaris leaves powder, for methylene blue adsorption from aqueous solution was investigated. The adsorbent surface was examined using SEM and FTIR techniques. The experiments were conducted, in batch system, to find out the effect of pH, contact time, adsorbent dose, initial dye concentration, temperature and ionic strength on dye adsorption. The process is best described by Langmuir isotherm and the pseudo second order kinetic model. Maximum adsorption capacity, 188.2 (mg g^-1), is better than other similar adsorbent materials. Thermodynamic parameters revealed a spontaneous and endothermic process, suggesting a physisorption mechanism. A Taguchi orthogonal array (L₂₇) experimental design was used to determine the optimum conditions for the removal of dye. Various desorbing agents were used to investigate the regeneration possibility of used adsorbent. Results suggest that the adsorbent material is very effective for removal of methylene blue from aqueous solutions.

SUBMITTER: Mosoarca G

PROVIDER: S-EPMC7810873 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Syringa vulgaris leaves powder a novel low-cost adsorbent for methylene blue removal: isotherms, kinetics, thermodynamic and optimization by Taguchi method.

Mosoarca Giannin G Vancea Cosmin C Popa Simona S Gheju Marius M Boran Sorina S

Scientific reports 20201019 1

In this study, the potential of a new low-cost adsorbent, Syringa vulgaris leaves powder, for methylene blue adsorption from aqueous solution was investigated. The adsorbent surface was examined using SEM and FTIR techniques. The experiments were conducted, in batch system, to find out the effect of pH, contact time, adsorbent dose, initial dye concentration, temperature and ionic strength on dye adsorption. The process is best described by Langmuir isotherm and the pseudo second order kinetic m ...[more]

PMID: 33077788

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Project description:A promising alternative to antibiotics for treatment of Staphylococcus aureus infections is photodynamic inactivation (PDI), which employs a photosensitizer (PS) that produces cytotoxic reactive oxygen species (ROS) when exposed to molecular oxygen and antimicrobial blue light in the spectrum of 400-470 nm. Although the precise mechanistic basis of PDI has not been defined, the formation of ROS and free radicals that oxidize a number of cellular targets, including membrane lipids, damage to proteins and nucleic acids result in inactivation of essential cellular functions and subsequent cell death. Because PDI is non-selective and affects multiple cellular targets, development of resistance or tolerance to PDI has been considered to be unlikely and attempts to induce S. aureus resistance or tolerance upon repeated sub-lethal doses of PDI have not succeeded. However, multiple aspects of PDI suggest that development of tolerance is highly probable, in particular when PDI is used for treatment of infections where the environment at the infection site prevents penetration of PDI at a level sufficient to cause death of all bacteria and with tolerant phenotypes emerging from the surviving bacteria. In this study, we sought to identify the mechanisms that contribute to PDI tolerance in S. aureus. S. aureus HG003 and the isogenic HG003DmutSL strain with defects in DNA mismatch repair were used to evaluate the response of S. aureus and the roles of DNA mismatch repair and gene regulatory networks to repeated sublethal doses of PDI. Global transcriptome and genome analyses were used in an agnostic approach to identify the underlying transcriptional responses and genetic adaptations that occur as a result of repeated PDI and contribute to PDI tolerance. Our results reveal multiple metabolic, transport and cell wall biogenesis pathways that contribute to PDI tolerance, and a S. aureus regulatory gene likely responsible for the adaptive transcriptional response to PDI.

Dataset Information

Syringa vulgaris leaves powder a novel low-cost adsorbent for methylene blue removal: isotherms, kinetics, thermodynamic and optimization by Taguchi method.

Publications

Syringa vulgaris leaves powder a novel low-cost adsorbent for methylene blue removal: isotherms, kinetics, thermodynamic and optimization by Taguchi method.

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