Fast Delayed Emission in New Pyridazine-Based Compounds.
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ABSTRACT:
SUBMITTER: Krotkus S
PROVIDER: S-EPMC7817954 | biostudies-literature | 2020
REPOSITORIES: biostudies-literature
Publications
Fast Delayed Emission in New Pyridazine-Based Compounds.
Krotkus Simonas S Matulaitis Tomas T Diesing Stefan S Copley Graeme G Archer Emily E Keum Changmin C Cordes David B DB Slawin Alexandra M Z AMZ Gather Malte C MC Zysman-Colman Eli E Samuel Ifor D W IDW
Frontiers in chemistry 20210107
Three novel donor-acceptor molecules comprising the underexplored pyridazine (Pydz) acceptor moiety have been synthesized and their structural, electrochemical and photophysical properties thoroughly characterized. Combining Pydz with two phenoxazine donor units linked via a phenyl bridge in a <i>meta</i> configuration (<b>dPXZMePydz</b>) leads to high reverse intersystem crossing rate <i>k</i> <sub>RISC</sub> = 3.9 · 10<sup>6</sup> s<sup>-1</sup> and fast thermally activated delayed fluorescenc ...[more]
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