Ontology highlight
ABSTRACT:
SUBMITTER: Ramler J
PROVIDER: S-EPMC7818483 | biostudies-literature | 2020 Aug
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20200728 45
Three-coordinate cationic bismuth compounds [Bi(diaryl)(EPMe<sub>3</sub> )][SbF<sub>6</sub> ] have been isolated and fully characterized (diaryl=[(C<sub>6</sub> H<sub>4</sub> )<sub>2</sub> C<sub>2</sub> H<sub>2</sub> ]<sup>2-</sup> , E=S, Se). They represent rare examples of molecular complexes with Bi⋅⋅⋅EPR<sub>3</sub> interactions (R=monoanionic substituent). The <sup>31</sup> P NMR chemical shift of EPMe<sub>3</sub> has been found to be sensitive to the formation of LA⋅⋅⋅EPMe<sub>3</sub> Lewi ...[more]