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Reversible Reductive Elimination in Aluminum(II) Dihydrides.


ABSTRACT: Oxidative addition and reductive elimination are defining reactions of transition-metal organometallic chemistry. In main-group chemistry, oxidative addition is now well-established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving AlI and AlIII intermediates.

SUBMITTER: Falconer RL 

PROVIDER: S-EPMC7894477 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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Reversible Reductive Elimination in Aluminum(II) Dihydrides.

Falconer Rosalyn L RL   Nichol Gary S GS   Smolyar Ivan V IV   Cockroft Scott L SL   Cowley Michael J MJ  

Angewandte Chemie (International ed. in English) 20201124 4


Oxidative addition and reductive elimination are defining reactions of transition-metal organometallic chemistry. In main-group chemistry, oxidative addition is now well-established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al<sup>I</sup> and Al<sup>III</sup> intermediates. ...[more]

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