Ontology highlight
ABSTRACT:
SUBMITTER: Falconer RL
PROVIDER: S-EPMC7894477 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
Falconer Rosalyn L RL Nichol Gary S GS Smolyar Ivan V IV Cockroft Scott L SL Cowley Michael J MJ
Angewandte Chemie (International ed. in English) 20201124 4
Oxidative addition and reductive elimination are defining reactions of transition-metal organometallic chemistry. In main-group chemistry, oxidative addition is now well-established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al<sup>I</sup> and Al<sup>III</sup> intermediates. ...[more]