Unknown

Dataset Information

0

Reversible Reductive Elimination in Aluminum(II) Dihydrides.

ABSTRACT: Oxidative addition and reductive elimination are defining reactions of transition-metal organometallic chemistry. In main-group chemistry, oxidative addition is now well-established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving AlI and AlIII intermediates.

SUBMITTER: Falconer RL 

PROVIDER: S-EPMC7894477 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Reversible Reductive Elimination in Aluminum(II) Dihydrides.

Falconer Rosalyn L RL   Nichol Gary S GS   Smolyar Ivan V IV   Cockroft Scott L SL   Cowley Michael J MJ  

Angewandte Chemie (International ed. in English) 20201124 4

Oxidative addition and reductive elimination are defining reactions of transition-metal organometallic chemistry. In main-group chemistry, oxidative addition is now well-established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al<sup>I</sup> and Al<sup>III</sup> intermediates. ...[more]

Similar Datasets

Unknown Force-modulated reductive elimination from platinum(ii) diaryl complexes.
| S-EPMC8386663 | biostudies-literature
Unknown Reversible Photoinduced Reductive Elimination of H2 from the Nitrogenase Dihydride State, the E(4)(4H) Janus Intermediate.
| S-EPMC4773049 | biostudies-literature
Unknown Reductive elimination from arylpalladium cyanide complexes.
| S-EPMC3360980 | biostudies-literature
Unknown Controlling Pd(IV) reductive elimination pathways enables Pd(II)-catalysed enantioselective C(sp3)-H fluorination.
| S-EPMC6289870 | biostudies-literature
Unknown Biaryl Phosphine Based Pd(II) Amido Complexes: The Effect of Ligand Structure on Reductive Elimination.
| S-EPMC5127253 | biostudies-literature
Unknown Insights into Cobalta(III/IV/II)-Electrocatalysis: Oxidation-Induced Reductive Elimination for Twofold C-H Activation.
| S-EPMC7318662 | biostudies-literature
Unknown A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination.
| S-EPMC5667502 | biostudies-literature
Unknown Bimetallic reductive elimination from dinuclear Pd(III) complexes.
| S-EPMC2954233 | biostudies-literature
Unknown Slow reductive elimination from arylpalladium parent amido complexes.
| S-EPMC2941907 | biostudies-literature
Unknown A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis-Pair and Reductive Elimination.
| S-EPMC7839681 | biostudies-literature