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Experimental and numerical perspective on the fire performance of MXene/Chitosan/Phytic acid coated flexible polyurethane foam.

ABSTRACT: Recent discoveries of two-dimensional transitional metal based materials have emerged as an excellent candidate for fabricating nanostructured flame-retardants. Herein, we report an eco-friendly flame-retardant for flexible polyurethane foam (PUF), which is synthesised by hybridising MXene (Ti[Formula: see text]) with biomass materials including phytic acid (PA), casein, pectin, and chitosan (CH). Results show that coating PUFs with 3 layers of CH/PA/Ti[Formula: see text] via layer-by-layer approach reduces the peak heat release and total smoke release by 51.1% and 84.8%, respectively. These exceptional improvements exceed those achieved by a CH/Ti[Formula: see text] coating. To further understand the fundamental flame and smoke reduction phenomena, a pyrolysis model with surface regression was developed to simulate the flame propagation and char layer. A genetic algorithm was utilised to determine optimum parameters describing the thermal degradation rate. The superior flame-retardancy of CH/PA/Ti[Formula: see text] was originated from the shielding and charring effects of the hybrid MXene with biomass materials containing aromatic rings, phenolic and phosphorous compounds.

SUBMITTER: Lin B

PROVIDER: S-EPMC7907131 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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Experimental and numerical perspective on the fire performance of MXene/Chitosan/Phytic acid coated flexible polyurethane foam.

Lin Bo B Yuen Anthony Chun Yin ACY Chen Timothy Bo Yuan TBY Yu Bin B Yang Wei W Zhang Jin J Yao Yin Y Wu Shuying S Wang Chun Hui CH Yeoh Guan Heng GH

Scientific reports 20210225 1

Recent discoveries of two-dimensional transitional metal based materials have emerged as an excellent candidate for fabricating nanostructured flame-retardants. Herein, we report an eco-friendly flame-retardant for flexible polyurethane foam (PUF), which is synthesised by hybridising MXene (Ti[Formula: see text]) with biomass materials including phytic acid (PA), casein, pectin, and chitosan (CH). Results show that coating PUFs with 3 layers of CH/PA/Ti[Formula: see text] via layer-by-layer appr ...[more]

PMID: 33633219

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Project description:This study aims to investigate the potential of integrating natural biochar (BC) derived from eggshell waste into flexible polyurethane (FPU) foam to enhance its mechanical and acoustic performance. The study explores the impact of incorporating BC at various weight ratios (0.1, 0.3, 0.5, and 0.7 wt. %) on the properties of the FPU foam. Additionally, the effects of modifying the BC with (3-aminopropyl)trimethoxysilane (APTMS) at different ratios (10, 20, and 30 wt. %) and the influence of diverse particle sizes of BC on the thermal, mechanical, and acoustic characteristics of the FPU composite are investigated. The functional groups, morphology, and elemental composition of the developed FPU composites are analyzed using Fourier-transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FESEM), and energy-dispersive X-ray (EDX) techniques. Characteristics such as density, gel fraction, and porosity were also assessed. The results reveal that the density of FPU foam increased by 4.32% and 7.83% while the porosity decreased to 50.22% and 47.05% with the addition of 0.1 wt. % of unmodified BC and modified BC with 20 wt. % APTMS, respectively, compared to unfilled FPU. Additionally, the gel fraction of the FPU matrix increases by 1.91% and 3.55% with the inclusion of 0.1 wt. % unmodified BC and modified BC with 20 wt. % APTMS, respectively. Furthermore, TGA analysis revealed that all FPU composites demonstrate improved thermal stability compared to unfilled FPU, reaching a peak value of 312.17°C for the FPU sample incorporating BC modified with 20 wt. % APTMS. Compression strength increased with 0.1 wt. % untreated BC but decreased at higher concentrations. Modifying BC with 20% APTMS resulted in an 8.23% increase in compressive strength compared to unfilled FPU. Acoustic analysis showed that the addition of BC improved absorption, and modified BC enhanced absorption characteristics of FPU, reaching Class D with a 20 mm thickness. BC modified with APTMS further improved acoustic properties compared to the unfilled FPU sample (Class E), with 20% modification showing the best results. These composites present promising materials for sound absorption applications and address environmental issues related to eggshell waste.

Dataset Information

Experimental and numerical perspective on the fire performance of MXene/Chitosan/Phytic acid coated flexible polyurethane foam.

Publications

Experimental and numerical perspective on the fire performance of MXene/Chitosan/Phytic acid coated flexible polyurethane foam.

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