Ontology highlight
ABSTRACT:
SUBMITTER: Haketa Y
PROVIDER: S-EPMC7914842 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Haketa Yohei Y Maeda Hiromitsu H
Molecules (Basel, Switzerland) 20210206 4
Dipyrrolyldiketones are essential building units of anion-responsive π-electronic molecules and ion-pairing assemblies. Here, we demonstrated that they form complexes with Cu<sup>II</sup> characterized by planar geometries. The solid-state stacking assembled structures, as revealed by single-crystal X-ray analysis, were modulated by the substitution of pyrrole units. The rectangular shapes of the Cu<sup>II</sup> complexes resulted in the formation of mesophases upon introduction of aliphatic cha ...[more]