Hydrogen-bonded nickel(I) complexes.

ABSTRACT: A series of nickel(ii) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(i) state provided access to an unusual nickel(i) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.

SUBMITTER: Wilson JR 

PROVIDER: S-EPMC7931650 | biostudies-literature |

REPOSITORIES: biostudies-literature