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Influence of the Prepolymer Type and Synthesis Parameters on Self-Healing Anticorrosion Properties of Composite Coatings Containing Isophorone Diisocyanate-Loaded Polyurethane Microcapsules.

ABSTRACT: Self-healing anticorrosion composite coatings containing isophorone diisocyanate-loaded polyurethane microcapsules were developed, and comprehensive research on prepolymer and microcapsules synthesis, as well as functional composite coatings preparation and characterization, was performed. The influence of the prepolymer type and the concentration of the stabilizing agent used in the synthesis procedure on the properties of the microcapsules was studied in detail. For this purpose, three different prepolymers were prepared from toluene-2,4-diisocyanate (TDI) and either glycerol, 1,4-butanediol, or 1,6-hexanediol, and their chemical properties were investigated. Microcapsules were synthesized from the obtained prepolymers, according to the oil-in-water polymerization method, where 1,6-hexanediol was used as a chain extender, while the concentration of the stabilizing agent in the synthesis procedure was varied. Microcapsules prepared from TDI-glycerol prepolymer, synthesized in the presence of 10 wt% of the stabilizing agent, showed superior chemical, morphological, and thermo-gravimetrical properties; thus, they were incorporated into the coating in the concentration of 20 wt%. The prepared composite coatings demonstrated self-healing and anticorrosion properties, and thus the developed microcapsules show great potential for the incorporation into the composite anticorrosion coatings at critical points where damage can easily occur, providing longer and more efficient anticorrosion protection.

SUBMITTER: Sobak M

PROVIDER: S-EPMC7967154 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Polyethylene Glycol-Isophorone Diisocyanate Polyurethane Prepolymers Tailored Using MALDI MS.

Project description:The reaction of diols with isocyanates, leading to mono-functional and di-functional prepolymers may be investigated using various characterization methods which show the overall conversion of isocyanate monomers. On the other hand, matrix-assisted laser desorption ionization mass spectrometry (MALDI MS) polymer characterization can be employed to identify the monomer units, the end-group functionalities, molecular weight averages, and to determine the copolymer sequence. Herein, we focus on prepolymer synthesis using isophorone diisocyanate (IPDI), a widely used diisocyanate for prepolymers preparation, especially in waterborne polyurethane materials. Thus, the reaction between polyethylene glycol diol and IPDI was in-depth investigated by mass spectrometry to determine the influence of the reaction parameters on the prepolymer's structure. The relative content of the different functional oligomer species at given reaction times was determined in the reaction mixture. More specifically, the offline analysis revealed the influence of reaction parameters such as reaction temperature, the concentration of reactants, and the amount of dibutyltin dilaurate catalyst. The established MALDI MS analysis involved measurements of samples, first, directly collected from the reaction mixture and secondly, following derivatization with methanol. The obtained results revealed the effects of reaction parameters on the functionalization reaction with isocyanates, allowing to achieve a better reaction control.

| S-EPMC9862538 | biostudies-literature

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| S-EPMC6680642 | biostudies-literature

Multifunctional Waterborne Polyurethane Microreactor-Based Approach to Fluorocarbon Composite Latex Coatings with Double Self-Healing and Excellent Synergistic Performances.

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| S-EPMC8059680 | biostudies-literature

From Scratch Closure to Electrolyte Barrier Restoration in Self-Healing Polyurethane Coatings.

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| S-EPMC8154210 | biostudies-literature

Design, Preparation and Properties of Polyurethane Dispersions via Prepolymer Method.

Project description:A waterborne polyurethane dispersion for foamed synthetic leather base was designed and prepared using prepolymer method. There are many variables in the emulsification and chain-extension process of waterborne polyurethane (WPUR) dispersions prepared by prepolymer method. This work thoroughly evaluated the impacts of the steps of adding emulsified water, the temperature of the prepolymer and emulsified water, and concentration of ammonia water on WPUR dispersions by investigating the particle sizes/distributions and the mechanical stability. Changes in the temperature of the prepolymer and emulsified water, the concentration of ammonia water, and the step of adding emulsified water showed great impacts on the appearance and particle size of dispersions. Decreasing the temperature of the prepolymer and emulsified water and increasing the dilution ration of H2O to ethylenediamine (EDA) led to safe emulsification and dispersions with good appearance and narrow particle size distributions can be prepared. Surprising results were obtained by adding emulsified water in two steps, WPUR dispersions with a small particle size, narrow particle distribution and excellent tensile properties can be obtained. The optimized WPUR1 was applied to prepare water-based synthetic leather base after mechanical foaming, and the base presented the desired high performance, such as high folding resistance and peel strength.

| S-EPMC9863305 | biostudies-literature

Repeatable Self-Healing of a Protective Coating Based on Vegetable-Oil-Loaded Microcapsules.

Project description:Generally, microcapsule-based self-healing materials have the limitation of single local self-healing. A few studies have reported repeatable self-healing in these microcapsular materials, but there is a challenge to develop multi-cycle self-healing materials that have the advantages of easier preparation and a more efficient operation. In this work, a mixture of two vegetable oils, soybean and olive oil, was used as a healing agent. The atmospheric oxygen-induced reaction behavior (in the presence of a catalyst) was investigated for various compositions of the vegetable oil mixtures; infrared spectroscopy, recovery testing, and viscoelasticity measurement were performed to find an optimum composition of the healing agent. Microcapsules loaded with soybean oil and catalyst-containing olive oil were separately prepared and used to prepare a dual-capsule self-healing coating. It was demonstrated through optical and scanning electron microscopy that, upon scribing the self-healing coating, the vegetable oils flowed out from microcapsules to self-heal the damaged area. When the healed area of the self-healing coating was re-scribed, self-healing was repeated, which was confirmed by scanning electron microscopy (SEM) and anticorrosion and electrochemical testing. Our new repeatable self-healing coating provides the merits of easy preparation, no need for external intervention such as light irradiation, and an environmentally-friendly nature.

| S-EPMC9146027 | biostudies-literature

Research on the Thermal Decomposition Reaction Kinetics and Mechanism of Pyridinol-Blocked Isophorone Diisocyanate.

Project description:A series of pyridinol-blocked isophorone isocyanates, based on pyridinol including 2-hydroxypyridine, 3-hydroxypyridine, and 4-hydroxypyridine, was synthesized and characterized by ¹H-NMR, 13C-NMR, and FTIR spectra. The deblocking temperature of blocked isocyanates was established by thermo-gravimetric analysis (TGA), differential scanning calorimetry (DSC), and the CO₂ evaluation method. The deblocking studies revealed that the deblocking temperature was increased with pyridinol nucleophilicity in this order: 3-hydroxypyridine > 4-hydroxypyridine > 2-hydroxypyridine. The thermal decomposition reaction of 4-hydroxypyridine blocked isophorone diisocyanate was studied by thermo-gravimetric analysis. The Friedman-Reich-Levi (FRL) equation, Flynn-Wall-Ozawa (FWO) equation, and Crane equation were utilized to analyze the thermal decomposition reaction kinetics. The activation energy calculated by FRL method and FWO method was 134.6 kJ·mol-1 and 126.2 kJ·mol-1, respectively. The most probable mechanism function calculated by the FWO method was the Jander equation. The reaction order was not an integer because of the complicated reactions of isocyanate.

| S-EPMC5456470 | biostudies-literature

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