Browse
Submit Data
Databases
API
Help

Dataset Information

29 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

6FDA-DAM:DABA Co-Polyimide Mixed Matrix Membranes with GO and ZIF-8 Mixtures for Effective CO₂/CH₄ Separation.

ABSTRACT: This work presents the gas separation evaluation of 6FDA-DAM:DABA (3:1) co-polyimide and its enhanced mixed matrix membranes (MMMs) with graphene oxide (GO) and ZIF-8 (particle size of <40 nm). The 6FDA-copolyimide was obtained through two-stage poly-condensation polymerization, while the ZIF-8 nanoparticles were synthesized using the dry and wet method. The MMMs were preliminarily prepared with 1-4 wt.% GO and 5-15 wt.% ZIF-8 filler loading independently. Based on the best performing GO MMM, the study proceeded with making MMMs based on the mixtures of GO and ZIF-8 with a fixed 1 wt.% GO content (related to the polymer matrix) and varied ZIF-8 loadings. All the materials were characterized thoroughly using TGA, FTIR, XRD, and FESEM. The gas separation was measured with 50:50 vol.% CO₂:CH₄ binary mixture at 2 bar feed pressure and 25 °C. The pristine 6FDA-copolyimide showed CO₂ permeability (P_CO2) of 147 Barrer and CO₂/CH₄ selectivity (α_CO2/CH4) of 47.5. At the optimum GO loading (1 wt.%), the P_CO2 and α_CO2/CH4 were improved by 22% and 7%, respectively. A combination of GO (1 wt.%)/ZIF-8 fillers tremendously improves its P_CO2; by 990% for GO/ZIF-8 (5 wt.%) and 1.124% for GO/ZIF-8 (10 wt.%). Regrettably, the MMMs lost their selectivity by 16-55% due to the non-selective filler-polymer interfacial voids. However, the hybrid MMM performances still resided close to the 2019 upper bound and showed good performance stability when tested at different feed pressure conditions.

SUBMITTER: Jain A

PROVIDER: S-EPMC7999237 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Tailoring CO2/CH4 Separation Performance of Mixed Matrix Membranes by Using ZIF-8 Particles Functionalized with Different Amine Groups.

Project description:CO2 separation from CH4 by using mixed matrix membranes has received great attention due to its higher separation performance compared to neat polymeric membrane. However, Robeson's trade-off between permeability and selectivity still remains a major challenge for mixed matrix membrane in CO2/CH4 separation. In this work, we report the preparation, characterization and CO2/CH4 gas separation properties of mixed matrix membranes containing 6FDA-durene polyimide and ZIF-8 particles functionalized with different types of amine groups. The purpose of introducing amino-functional groups into the filler is to improve the interaction between the filler and polymer, thus enhancing the CO2 /CH4 separation properties. ZIF-8 were functionalized with three differents amino-functional group including 3-(Trimethoxysilyl)propylamine (APTMS), N-[3-(Dimethoxymethylsilyl)propyl ethylenediamine (AAPTMS) and N1-(3-Trimethoxysilylpropyl) diethylenetriamine (AEPTMS). The structural and morphology properties of the resultant membranes were characterized by using different analytical tools. Subsequently, the permeability of CO2 and CH4 gases over the resultant membranes were measured. The results showed that the membrane containing 0.5 wt% AAPTMS-functionalized ZIF-8 in 6FDA- durene polymer matrix displayed highest CO2 permeability of 825 Barrer and CO2/CH4 ideal selectivity of 26.2, which successfully lies on Robeson upper bound limit.

| S-EPMC6960569 | biostudies-literature

Efficient Separation of Acetylene-Containing Mixtures Using ZIF-8 Membranes.

Project description:Metal-organic framework (MOF) membranes show great potential in the separation of acetylene mixtures. In this work, we have prepared ZIF-8 membranes on polyamide (PA) substrates for the highly selective separation of acetylene/methane and acetylene/carbon dioxide mixtures. The C2H2/CH4 and C2H2/CO2 mixtures can be successfully separated using the ZIF-8 membranes, with separation factors of 12.1 and 1.8, respectively. Based on the results of the cross-permeation tests of C2H2/CH4, CO2/CH4, and C2H2/CO2, the separation mechanism of C2H2/CH4 in our ZIF-8 membrane can be attributed to a higher affinity for acetylene and molecular sieving effect, while C2H2/CO2 separation is related to thermodynamic factors. It is worth noting that this is the first example of MOF membranes to successfully separate C2H2 from CH4 and CO2.

| S-EPMC8655891 | biostudies-literature

Influence of Casting Solvents on CO2/CH4 Separation Using Polysulfone Membranes.

Project description:Polysulfone membranes exhibit resistance to high temperature with low manufacturing cost and high efficiency in the separation process. The composition of gases is an important step that estimates the efficiency of separation in membranes. As membrane types are currently becoming in demand for CO2/CH4 segregation, polysulfone will be an advantageous alternative to have in further studies. Therefore, research is undertaken in this study to evaluate two solvents: chloroform (CF) and tetrahydrofuran (THF). These solvents are tested for casting polymeric membranes from polysulfone (PSF) to separate every single component from a binary gas mixture of CO2/CH4. In addition, the effect of gas pressure was conducted from 1 to 10 bar on the behavior of the permeability and selectivity. The results refer to the fact that the maximum permeability of CO2 and CH4 for THF is 62.32 and 2.06 barrer at 1 and 2 bars, respectively. Further, the maximum permeability of CF is 57.59 and 2.12 barrer at 1 and 2 bars, respectively. The outcome selectivity values are 48 and 36 for THF and CF at 1 bar, accordingly. Furthermore, the study declares that with the increase in pressure, the permeability and selectivity values drop for CF and THF. The performance for polysulfone (PSF) membrane that is manufactured with THF is superior to that of CF relative to the Robeson upper bound. Therefore, through the results, it can be deduced that the solvent during in-situ synthesis has a significant influence on the gas separation of a binary mixture of CO2/CH4.

| S-EPMC8070651 | biostudies-literature

CO2/CH4 and H2/CH4 Gas Separation Performance of CTA-TNT@CNT Hybrid Mixed Matrix Membranes.

Project description:This study explored the underlying synergy between titanium dioxide nanotube (TNT) and carbon nanotube (CNT) hybrid fillers in cellulose triacetate (CTA)-based mixed matrix membranes (MMMs) for natural gas purification. The CNT@TNT hybrid nanofillers were blended with CTA polymer and cast as a thin film by a facile casting technique, after which they were used for single gas separation. The hybrid filler-based membrane depicted a higher CO2 uptake affinity than the single filler (CNT/TNT)-based membrane. The gas separation results indicate that the hybrid fillers (TNT@CNT) are strongly selective for CO2 over CH4 and H2 over CH4. The increment in the CO2/CH4 and H2/CH4 selectivities compared to the pristine CTA membrane was 42.98 from 25.08 and 48.43 from 36.58, respectively. Similarly, the CO2 and H2 permeability of the CTA-TNT@CNT membrane increased by six- and five-fold, respectively, compared to the pristine CTA membrane. Such significant improvements in CO2/CH4 and H2/CH4 separation performance and thermal and mechanical properties suggest a feasible and practical approach for potential biogas upgrading and natural gas purification.

| S-EPMC8625587 | biostudies-literature

Pebax/Modified Cellulose Nanofiber Composite Membranes for Highly Enhanced CO2/CH4 Separation

Project description: Not available

| S-EPMC10701723 | biostudies-literature

A Facile Synthesis of (PIM-Polyimide)-(6FDA-Durene-Polyimide) Copolymer as Novel Polymer Membranes for CO2 Separation.

Project description:Random copolymers made of both (PIM-polyimide) and (6FDA-durene-PI) were prepared for the first time by a facile one-step polycondensation reaction. By combining the highly porous and contorted structure of PIM (polymers with intrinsic microporosity) and high thermomechanical properties of PI (polyimide), the membranes obtained from these random copolymers [(PIM-PI)-(6FDA-durene-PI)] showed high CO2 permeability (>1047 Barrer) with moderate CO2/N2 (> 16.5) and CO2/CH4 (> 18) selectivity, together with excellent thermal and mechanical properties. The membranes prepared from three different compositions of two comonomers (1:4, 1:6 and 1:10 of x:y), all showed similar morphological and physical properties, and gas separating performance, indicating ease of synthesis and practicability for production in large scale. The gas separation performance of these membranes at various pressure ranges (100-1500 torr) was also investigated.

| S-EPMC6780089 | biostudies-literature

Development of CO2-Selective Polyimide-Based Gas Separation Membranes Using Crown Ether and Polydimethylsiloxane.

Project description:A series of CO2-selective polyimides (CE-PDMS-PI-x) was synthesized by copolymerizing crown ether diamine (trans-diamino-DB18C6) and PDMS-diamine with 4,4'-(hexafluoroisopropylidene) di-phthalic anhydride (6FDA) through the polycondensation reaction. The structural characteristics of the copolymers and corresponding membranes were characterized by nuclear magnetic resonance (NMR), infrared spectroscopy (ATR-FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD), and gel permeation chromatography (GPC). The effect of PDMS loading on the CE-PDMS-PI-x copolymers was further analyzed and a very good structure-property relationship was found. A well-distributed soft PDMS unit played a key role in the membrane's morphology, in which improved CO2-separation performance was observed at a low PDMS content (5 wt %). In contrast, the fine-grained phase separation adversely affected the separation behavior at a certain level of PDMS loading, and the PDMS was found to provide a flexible gas-diffusion path, affecting only the permeability without changing the selective gas-separation performance for the copolymers with a PDMS content of 20% or above.

| S-EPMC8227709 | biostudies-literature

CO2/N2 Separation Properties of Polyimide-Based Mixed-Matrix Membranes Comprising UiO-66 with Various Functionalities.

Project description:Nanocrystalline UiO-66 and its derivatives (containing -NH2, -Br, -(OH)2) were developed via pre-synthetic functionalization and incorporated into a polyimide membrane to develop a mixed-matrix membrane (MMM) for CO2/N2 separation. Incorporation of the non-functionalized UiO-66 nanocrystals into the polyimide membrane successfully improved CO2 permeability, with a slight decrease in CO2/N2 selectivity, owing to its large accessible surface area. The addition of other functional groups further improved the CO2/N2 selectivity of the polymeric membrane, with UiO-66-NH2, UiO-66-Br, and UiO-66-(OH)2 demonstrating improvements of 12%, 4%, and 17%, respectively. Further evaluation by solubility-diffusivity analysis revealed that the functionalized UiO-66 in MMMs can effectively increase CO2 diffusivity while suppressing N2 sorption, thus, resulting in improved CO2/N2 selectivity. Such results imply that the structural tuning of UiO-66 by the incorporation of various functional groups is an effective strategy to improve the CO2 separation performance of MMMs.

| S-EPMC7407110 | biostudies-literature

Key Applications and Potential Limitations of Ionic Liquid Membranes in the Gas Separation Process of CO2, CH4, N2, H2 or Mixtures of These Gases from Various Gas Streams.

Project description:Heightened levels of carbon dioxide (CO2) and other greenhouse gases (GHGs) have prompted research into techniques for their capture and separation, including membrane separation, chemical looping, and cryogenic distillation. Ionic liquids, due to their negligible vapour pressure, thermal stability, and broad electrochemical stability have expanded their application in gas separations. This work provides an overview of the recent developments and applications of ionic liquid membranes (ILMs) for gas separation by focusing on the separation of carbon dioxide (CO2), methane (CH4), nitrogen (N2), hydrogen (H2), or mixtures of these gases from various gas streams. The three general types of ILMs, such as supported ionic liquid membranes (SILMs), ionic liquid polymeric membranes (ILPMs), and ionic liquid mixed-matrix membranes (ILMMMs) for the separation of various mixed gas systems, are discussed in detail. Furthermore, issues, challenges, computational studies and future perspectives for ILMs are also considered. The results of the analysis show that SILMs, ILPMs, and the ILMMs are very promising membranes that have great potential in gas separation processes. They offer a wide range of permeabilities and selectivities for CO2, CH4, N2, H2 or mixtures of these gases. In addition, a comparison was made based on the selectivity and permeability of SILMs, ILPMs, and ILMMMs for CO2/CH4 separation based on a Robeson's upper bound curves.

| S-EPMC7570638 | biostudies-literature

"All Polyimide" Mixed Matrix Membranes for High Performance Gas Separation.

Project description:To improve the interfacial compatibility of mixed matrix membranes (MMMs) for gas separation, microporous polyimide particle (AP) was designed, synthesized, and introduced into intrinsic microporous polyimide matrix (6FDA-Durene) to form "all polyimide" MMMs. The AP fillers showed the feature of thermal stability, similar density with polyimide matrix, high porosity, high fractional free volume, large microporous dimension, and interpenetrating network architecture. As expected, the excellent interfacial compatibility between 6FDA-Durene and AP without obvious agglomeration even at a high AP loading of 10 wt.% was observed. As a result, the CO2 permeability coefficient of MMM with AP loading as low as 5 wt.% reaches up to 1291.13 Barrer, which is 2.58 times that of the pristine 6FDA-Durene membrane without the significant sacrificing of ideal selectivity of CO2/CH4. The improvement of permeability properties is much better than that of the previously reported MMMs, where high filler content is required to achieve a high permeability increase but usually leads to significant agglomeration or phase separation of fillers. It is believed that the excellent interfacial compatibility between the PI fillers and the PI matrix induce the effective utilization of porosity and free volume of AP fillers during gas transport. Thus, a higher diffusion coefficient of MMMs has been observed than that of the pristine PI membrane. Furthermore, the rigid polyimide fillers also result in the excellent anti-plasticization ability for CO2. The MMMs with a 10 wt.% AP loading shows a CO2 plasticization pressure of 300 psi.

| S-EPMC8073420 | biostudies-literature