Different Phenomena in Magnetic/Electrical Properties of Co(II) and Ni(II) Isomorphous MOFs.

ABSTRACT: Two unprecedented and stable metal-organic frameworks, {[Co₂(H₂O)₂(L)(OH)]·2.5H₂O·0.5DMF} _n (1) and {[Ni₂(H₂O)₂(L)(OH)]·1.75H₂O} _n (2), have been synthesized (H₃L = 5-(5-carboxy-pyridin-3-yloxy)-isophthalic acid, DMF = N,N-dimethylformamide). Structural analysis shows that 1 and 2 are heteronuclear isomorphous, possessing a three-dimensional (3D) (4,8)-connected flu/fluorite topological framework formed through the interconnection of tetranuclear butterfly {M₄(COO)₆(OH)₂} clusters and the ligands. Although the frameworks of these two compounds are similar, their magnetic properties are different. Compound 1 exhibits an antiferromagnetic interaction in the high-temperature region, while 2 shows a weak ferromagnetic interaction in the whole-temperature region. Furthermore, considering the presence of hydroxyl groups and water molecules in the frameworks, we tested their proton conductivity. The efficient proton transfer pathway in the framework endowed 1 and 2 with excellent proton conductivities of 9.07 × 10^-5 and 1.29 × 10^-4 S·cm^-1 at 363 K and 98% relative humidity (RH), respectively.

SUBMITTER: Li SF 

PROVIDER: S-EPMC8028129 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature