Ontology highlight
ABSTRACT:
SUBMITTER: Nowok A
PROVIDER: S-EPMC8034769 | biostudies-literature | 2021 Mar
REPOSITORIES: biostudies-literature
Nowok Andrzej A Dulski Mateusz M Grelska Joanna J Szeremeta Anna Z AZ Jurkiewicz Karolina K Grzybowska Katarzyna K Musiał Małgorzata M Pawlus Sebastian S
The journal of physical chemistry letters 20210224 8
A series of five alcohols (3-methyl-2-butanol, 1-cyclopropylethanol, 1-cyclopentylethanol, 1-cyclohexylethanol, and 1-phenylethanol) was used to study the impact of the size of steric hindrance and its aromaticity on self-assembling phenomena in the liquid phase. In this Letter, we have explicitly shown that the phenyl ring exerts a much stronger effect on the self-organization of molecules via the O-H···O scheme than any other type of steric hindrance, leading to a significant decline in the si ...[more]