Effect of Alkaline Salts on Calcium Sulfoaluminate Cement Hydration.
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ABSTRACT:
SUBMITTER: Tambara Junior LUD
PROVIDER: S-EPMC8037319 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:The hydration of cement is often modeled as a phase boundary nucleation and growth (pBNG) process. Classical pBNG models, based on the use of isotropic and constant growth rate of the main hydrate, that is, calcium-silicate-hydrate (C-S-H), are unable to explain the lack of any significant effect of the water-to-cement (w/c) ratio on the hydration kinetics of cement. This paper presents a modified form of the pBNG model, in which the anisotropic growth of C-S-H is allowed to vary in relation to the nonlinear evolution of its supersaturation in solution. Results show that once the supercritical C-S-H nuclei form, their growth remains confined within a region in proximity to the cement particles. This is hypothesized to be a manifestation of the sedimentation of cement particles, which imposes a space constraint for C-S-H growth. In pastes wherein the sedimentation of cement particles is disrupted, the hydration kinetics are no longer unresponsive to changes in w/c. Unlike C-S-H, the ions in solution are not confined, and hence, the supersaturation-dependent growth rate of C-S-H diminishes monotonically with increasing w/c. Overall, the outcomes of this work highlight important aspects that need to be considered in employing pBNG models for simulating hydration of cement-based systems.
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Project description:This paper systematically studied the modification of cement-based materials by nano-SiO₂ particles with an average diameter of about 20 nm. In order to obtain the effect of nano-SiO₂ particles on the mechanical properties, hydration, and pore structure of cement-based materials, adding 1%, 3%, and 5% content of nano-SiO₂ in cement paste, respectively. The results showed that the reaction of nano-SiO₂ particles with Ca(OH)₂ (crystal powder) started within 1 h, and formed C-S-H gel. The reaction speed was faster after aging for three days. The mechanical properties of cement-based materials were improved with the addition of 3% nano-SiO₂, and the early strength enhancement of test pieces was obvious. Three-day compressive strength increased 33.2%, and 28-day compressive strength increased 18.5%. The exothermic peak of hydration heat of cement increased significantly after the addition of nano-SiO₂. Appearance time of the exothermic peak was advanced and the total heat release increased. Thermogravimetric-differential scanning calorimetry (TG-DSC) analysis showed that nano-SiO₂ promoted the formation of C-S-H gel. The results of mercury intrusion porosimetry (MIP) showed that the total porosity of cement paste with 3% nano-SiO₂ was reduced by 5.51% and 5.4% at three days and 28 days, respectively, compared with the pure cement paste. At the same time, the pore structure of cement paste was optimized, and much-detrimental pores and detrimental pores decreased, while less harmful pores and innocuous pores increased.
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Project description:Background. Mineral trioxide aggregate (MTA) and Calcium-enriched Mixture (CEM) cement are used for pulp capping since they induce the formation of a dentinal bridge. Long setting time is a shortcoming of these types of cement. This study aimed to assess the effect of the incorporation of some alkaline salts to MTA and CEM cement on their setting time, ion release profile, pH, and surface morphology. Methods. In this in vitro experimental study, 5% calcium chloride (CaCl2), calcium oxide (CaO), sodium fluoride (NaF), and calcium nitrate [Ca(NO3)2] were separately added to MTA and CEM cement. The primary and final setting times of the cements were measured using a Gillmore needle apparatus. The samples were immersed in simulated body fluid (SBF) for one, seven, and 14 days and subjected to x-ray diffraction (XRD) and scanning electron microscopy (SEM) for phase identification and surface morphology assessment. The change in the pH of solutions was studied, and the calcium ion release profile was determined using inductively coupled plasma atomic emission spectroscopy (ICP-AES). The data were analyzed with ANOVA, followed by post hoc tests. Results. CaCl2 and CaO decreased the setting time of MTA, and Ca(NO3)2 decreased the setting time of CEM cement. The incorporation of the salts increased the pH and calcium ion release from both cements, and hydroxyapatite deposits were noted to cover the surface of the samples (observed by SEM and confirmed by EDXA). Conclusion. The incorporation of CaCl2 and CaO into MTA and Ca(NO3)2 into CEM cement decreased their setting time and increased their pH and calcium ion release.
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Project description:Despite a century of research, our understanding of cement dissolution and precipitation processes at early ages is very limited. This is due to the lack of methods that can image these processes with enough spatial resolution, contrast and field of view. Here, we adapt near-field ptychographic nanotomography to in situ visualise the hydration of commercial Portland cement in a record-thick capillary. At 19 h, porous C-S-H gel shell, thickness of 500 nm, covers every alite grain enclosing a water gap. The spatial dissolution rate of small alite grains in the acceleration period, ∼100 nm/h, is approximately four times faster than that of large alite grains in the deceleration stage, ∼25 nm/h. Etch-pit development has also been mapped out. This work is complemented by laboratory and synchrotron microtomographies, allowing to measure the particle size distributions with time. 4D nanoimaging will allow mechanistically study dissolution-precipitation processes including the roles of accelerators and superplasticizers.
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Project description:This paper presents the results of comprehensive cement paste porosity and gas permeability tests. The tests conducted concerned ordinary Portland cement (OPC) cement pastes with varying water-cement ratios ranging from 0.3 to 0.6. The tests were conducted after the curing of cement paste for 90 days and two years under laboratory conditions. Open porosity was determined using three methods: helium pycnometry, mercury intrusion porosimetry, and water saturation. Permeability was determined using a modified RILEM-Cembureau method. The results obtained demonstrated that permeability does not change significantly over time despite the observed material shifts in open porosity characteristics caused both by further progress in hydration and by the carbonation process that occurs. The results of the tests conducted also permitted the quantitative determination of the impact of the water-cement ratio, age, and the progress of carbonation on open porosity measured using different methods and also on the gas permeability of the pastes.
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Project description:In hybrid alkaline fly ash cements, a new generation of binders, hydration, is characterized by features found in both ordinary portland cement (OPC) hydration and the alkali activation of fly ash (AAFA). Hybrid alkaline fly ash cements typically have a high fly ash (70 wt % to 80 wt %) and low clinker (20 wt % to 30 wt %) content. The clinker component favors curing at ambient temperature. A hydration mechanism is proposed based on the authors' research on these hybrid binders over the last five years. The mechanisms for OPC hydration and FA alkaline activation are summarized by way of reference. In hybrid systems, fly ash activity is visible at very early ages, when two types of gel are formed: C-S-H from the OPC and N-A-S-H from the fly ash. In their mutual presence, these gels tend to evolve, respectively, into C-A-S-H and (N,C)-A-S-H. The use of activators with different degrees of alkalinity has a direct impact on reaction kinetics but does not modify the main final products, a mixture of C-A-S-H and (N,C)-A-S-H gels. The proportion of each gel in the mix does, however, depend on the alkalinity generated in the medium.
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Project description:An alkali-activated blend of aluminum cement and class F fly ash is an attractive solution for geothermal wells where cement is exposed to significant thermal shocks and aggressive environments. Set-control additives enable the safe cement placement in a well but may compromise its mechanical properties. This work evaluates the effect of a tartaric-acid set retarder on phase composition, microstructure, and strength development of a sodium-metasilicate-activated calcium aluminate/fly ash class F blend after curing at 85 °C, 200 °C or 300 °C. The hardened materials were characterized with X-ray diffraction, thermogravimetric analysis, X-ray computed tomography, and combined scanning electron microscopy/energy-dispersive X-ray spectroscopy and tested for mechanical strength. With increasing temperature, a higher number of phase transitions in non-retarded specimens was found as a result of fast cement hydration. The differences in the phase compositions were also attributed to tartaric acid interactions with metal ions released by the blend in retarded samples. The retarded samples showed higher total porosity but reduced percentage of large pores (above 500 µm) and greater compressive strength after 300 °C curing. Mechanical properties of the set cements were not compromised by the retarder.
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Project description:This study investigated the material properties and hydration characteristics of calcium sulfoaluminate cement (CSA) based mortars cured under 3 different initial curing temperatures. Two CSA cements with different M-values were selected. Obtained experimental results of mechanical properties, dimensional stability, and heat release were explained by hydration characteristics from X-ray diffraction, thermal gravimetric analysis, porosimetry, and thermodynamic modeling. Decomposition of ettringite decreased compressive strength but re-formation of ettringite after additional curing at 30 °C helped to recover the strength in CSA cement with a high amount of calcium sulfate. CSA cement with a low amount of calcium sulfate which was designed to predominantly have monosulfate as the main hydration product, showed increased 1-day strength after higher temperature curing but this occurred was at the expense of decreased 28-day strength.
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