Unknown

Dataset Information

0

Hydrophosphination of boron-boron multiple bonds.


ABSTRACT: Five compounds containing boron-boron multiple bonds are shown to undergo hydrophosphination reactions with diphenylphosphine in the absence of a catalyst. With diborenes, the products obtained are highly dependent on the substitution pattern at the boron atoms, with both 1,1- and 1,2-hydrophosphinations observed. With a symmetrical diboryne, 1,2-hydrophosphination yields a hydro(phosphino)diborene. The different mechanistic pathways for the hydrophosphination of diborenes are rationalised with the aid of density functional theory calculations.

SUBMITTER: Stennett TE 

PROVIDER: S-EPMC8148080 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC6644692 | biostudies-literature
| S-EPMC7220893 | biostudies-literature
| S-EPMC3384763 | biostudies-literature
| S-EPMC4667194 | biostudies-literature
| S-EPMC5933228 | biostudies-literature
| S-EPMC5031991 | biostudies-literature
| S-EPMC6195222 | biostudies-literature
| S-EPMC4768074 | biostudies-literature
| S-EPMC5707506 | biostudies-literature
| S-EPMC7339525 | biostudies-literature