Enhanced CH₃OH selectivity in CO₂ hydrogenation using Cu-based catalysts generated via SOMC from Ga^III single-sites.

ABSTRACT: Small and narrowly distributed nanoparticles of copper alloyed with gallium supported on silica containing residual Ga^III sites can be obtained via surface organometallic chemistry in a two-step process: (i) formation of isolated Ga^III surface sites on SiO₂ and (ii) subsequent grafting of a Cu^I precursor, [Cu(O ^t Bu)]₄, followed by a treatment under H₂ to generate CuGa _x alloys. This material is highly active and selective for CO₂ hydrogenation to CH₃OH. In situ X-ray absorption spectroscopy shows that gallium is oxidized under reaction conditions while copper remains as Cu⁰. This CuGa material only stabilizes methoxy surface species while no formate is detected according to ex situ infrared and solid-state nuclear magnetic resonance spectroscopy.

SUBMITTER: Lam E 

PROVIDER: S-EPMC8159433 | biostudies-literature |

REPOSITORIES: biostudies-literature