Ontology highlight
ABSTRACT:
SUBMITTER: Panetti GB
PROVIDER: S-EPMC8179533 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Chemical science 20210203 12
The super electron donor (SED) ability of 2-azaallyl anions has recently been discovered and applied to diverse reactivity, including transition metal-free cross-coupling and dehydrogenative cross-coupling processes. Surprisingly, the redox properties of 2-azaallyl anions and radicals have been rarely studied. Understanding the chemistry of elusive species is the key to further development. Electrochemical analysis of phenyl substituted 2-azaallyl anions revealed an oxidation wave at <i>E</i> <s ...[more]