Ontology highlight
ABSTRACT:
SUBMITTER: Baumer N
PROVIDER: S-EPMC8179630 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Bäumer Nils N Kartha Kalathil K KK Buss Stefan S Maisuls Iván I Palakkal Jasnamol P JP Strassert Cristian A CA Fernández Gustavo G
Chemical science 20210223 14
Herein, we exploit coordination geometry as a new tool to regulate the non-covalent interactions, photophysical properties and energy landscape of supramolecular polymers. To this end, we have designed two self-assembled Pt(ii) complexes <b>1</b> and <b>2</b> that feature an identical aromatic surface, but differ in the coordination and molecular geometry (linear <i>vs.</i> V-shaped) as a result of judicious ligand choice (monodentate pyridine <i>vs.</i> bidentate bipyridine). Even though both c ...[more]