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Entropy Scaling of Viscosity - II: Predictive Scheme for Normal Alkanes.

ABSTRACT: In this work, a residual entropy value 6/10 of the way between the critical point and a value of -2/3 of Boltzmann's constant is shown to collapse the scaled viscosity for the family of normal alkanes. Based on this approach, a nearly universal correlation is proposed that can reproduce 95% of the experimental data for normal alkanes within ±18% (without removal of clearly erroneous data). This universal correlation has no new fluid-specific empirical parameters and is based on experimentally accessible values. This collapse is shown to be valid to a residual entropy half way between the critical point and the triple point, beyond which the macroscopically-scaled viscosity has a super-exponential dependence on residual entropy, terminating at the triple point. A key outcome of this study is a better understanding of entropy scaling for fluids with intramolecular degrees of freedom. A study of the transport and thermodynamic properties at the triple point rounds out the analysis.

SUBMITTER: Bell IH

PROVIDER: S-EPMC8191377 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Entropy Scaling of Viscosity - II: Predictive Scheme for Normal Alkanes.

Bell Ian H IH

Journal of chemical and engineering data 20201001 11

In this work, a residual entropy value 6/10 of the way between the critical point and a value of -2/3 of Boltzmann's constant is shown to collapse the scaled viscosity for the family of normal alkanes. Based on this approach, a nearly universal correlation is proposed that can reproduce 95% of the experimental data for normal alkanes within ±18% (without removal of clearly erroneous data). This universal correlation has no new fluid-specific empirical parameters and is based on experimentally ac ...[more]

PMID: 34121765

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