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Mn²⁺ induced significant improvement and robust stability of radioluminescence in Cs₃Cu₂I₅ for high-performance nuclear battery.

ABSTRACT: Fluorescent type nuclear battery consisting of scintillator and photovoltaic device enables semipermanent power source for devices working under harsh circumstances without instant energy supply. In spite of the progress of device structure design, the development of scintillators is far behind. Here, a Cs₃Cu₂I₅: Mn scintillator showing a high light yield of ~67000 ph MeV^-1 at 564 nm is presented. Doping and intrinsic features endow Cs₃Cu₂I₅: Mn with robust thermal stability and irradiation hardness that 71% or >95% of the initial radioluminescence intensity can be maintained in an ultra-broad temperature range of 77 K-433 K or after a total irradiation dose of 2590 Gy, respectively. These superiorities allow the fabrication of efficient and stable nuclear batteries, which show an output improvement of 237% respect to the photovoltaic device without scintillator. Luminescence mechanisms including self-trapped exciton, energy transfer, and impact excitation are proposed for the anomalous dramatic radioluminescence improvement. This work will open a window for the fields of nuclear battery and radiography.

SUBMITTER: Li X

PROVIDER: S-EPMC8222237 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Efficient and Reabsorption-Free Radioluminescence in Cs3Cu2I5 Nanocrystals with Self-Trapped Excitons.

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High-Performance Aqueous Zinc-Manganese Battery with Reversible Mn2+/Mn4+ Double Redox Achieved by Carbon Coated MnOx Nanoparticles.

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The optoelectronic properties improvement of double perovskites Cs2SnI6 by anionic doping (F-).

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Bandgap Modulation of Cs2AgInX6 (X = Cl and Br) Double Perovskite Nano- and Microcrystals via Cu2+ Doping.

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Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystals.

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Comparison of two MnIVMnIV-bis-μ-oxo complexes {[MnIV(N4(6-Me-DPEN))]2(μ-O)2}2+ and {[MnIV(N4(6-Me-DPPN))]2(μ-O)2}2.

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Mnx+ Substitution to Improve Na3V2(PO4)2F3-Based Electrodes for Sodium-Ion Battery Cathode.

Project description:Na3V2(PO4)2F3 (NVPF) is an extremely promising sodium storage cathode material for sodium-ion batteries because of its stable structure, wide electrochemical window, and excellent electrochemical properties. Nevertheless, the low ionic and electronic conductivity resulting from the insulated PO43- structure limits its further development. In this work, the different valence states of Mnx+ ions (x = 2, 3, 4) doped NVPF were synthesized by the hydrothermal method. A series of tests and characterizations reveals that the doping of Mn ions (Mn2+, Mn3+, Mn4+) changes the crystal structure and also affects the residual carbon content, which further influences the electrochemical properties of NVPF-based materials. The sodiation/desodiation mechanism was also investigated. Among them, the as-prepared NVPF doped with Mn2+ delivers a high reversible discharge capacity (116.2 mAh g-1 at 0.2 C), and the capacity retention of 67.7% after 400 cycles at 1 C was obtained. Such excellent performance and facile modified methods will provide new design ideas for the development of secondary batteries.

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Bright Blue Emitting Cu-Doped Cs2ZnCl4 Colloidal Nanocrystals.

Project description:We report here the synthesis of undoped and Cu-doped Cs2ZnCl4 nanocrystals (NCs) in which we could tune the concentration of Cu from 0.7 to 7.5%. Cs2ZnCl4 has a wide band gap (4.8 eV), and its crystal structure is composed of isolated ZnCl4 tetrahedra surrounded by Cs+ cations. According to our electron paramagnetic resonance analysis, in 0.7 and 2.1% Cu-doped NCs the Cu ions were present in the +1 oxidation state only, while in NCs at higher Cu concentrations we could detect Cu(II) ions (isovalently substituting the Zn(II) ions). The undoped Cs2ZnCl4 NCs were non emissive, while the Cu-doped samples had a bright intragap photoluminescence (PL) at ∼2.6 eV mediated by band-edge absorption. Interestingly, the PL quantum yield was maximum (∼55%) for the samples with a low Cu concentration ([Cu] ≤ 2.1%), and it systematically decreased when further increasing the concentration of Cu, reaching 15% for the NCs with the highest doping level ([Cu] = 7.5%). The same (∼2.55 eV) emission band was detected under X-ray excitation. Our density functional theory calculations indicated that the PL emission could be ascribed only to Cu(I) ions: these ions promote the formation of trapped excitons, through which an efficient emission takes place. Overall, these Cu-doped Cs2ZnCl4 NCs, with their high photo- and radio-luminescence emission in the blue spectral region that is free from reabsorption, are particularly suitable for applications in ionizing radiation detection.

| S-EPMC8016065 | biostudies-literature