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Efficient catalytic combustion of toluene at low temperature by tailoring surficial Pt⁰ and interfacial Pt-Al(OH)_x species.

ABSTRACT: Exploring highly efficient and low-cost supported Pt catalysts is attractive for the application of volatile organic compounds (VOCs) combustion. Herein, efficient catalytic combustion of toluene at low temperature over Pt/γ-Al₂O₃ catalysts has been demonstrated by tailoring active Pt species spatially. Pt/γ-Al₂O₃ catalyst with low Pt-content (0.26 wt%) containing both interfacial Pt-Al(OH)_x and surficial metallic Pt (Pt⁰) species exhibited super activity and water-resistant stability for toluene oxidation. The strong metal-support interaction located at the Al-OH-Pt interfaces elongated the Pt-O bond and contributed to the oxidation of toluene. Meanwhile, the OH group at the Al-OH-Pt interfaces had the strongest adsorption and activation capability for toluene and the derived intermediate species were subsequently oxidized by oxygen species activated by surficial Pt⁰ to yield carbon dioxide and water. This work initiated an inspiring sight to the design of active Pt species for the VOCs combustion.

SUBMITTER: Yu K

PROVIDER: S-EPMC8233202 | biostudies-literature |

REPOSITORIES: biostudies-literature

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