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In Situ Electric-Induced Switchable Transparency and Wettability on Laser-Ablated Bioinspired Paraffin-Impregnated Slippery Surfaces.

ABSTRACT: Switchable wetting and optical properties on a surface is synergistically realized by mechanical or temperature stimulus. Unfortunately, in situ controllable wettability together with programmable transparency on 2D/3D surfaces is rarely explored. Herein, Joule-heat-responsive paraffin-impregnated slippery surface (JR-PISS) is reported by the incorporation of lubricant paraffin, superhydrophobic micropillar-arrayed elastomeric membrane, and embedded transparent silver nanowire thin-film heater. Owing to its good flexibility, in situ controllable locomotion for diverse liquids on planar/curved JR-PISS is unfolded by alternately applying/discharging low electric-trigger of 6 V. Simultaneously, optical visibility can be reversibly converted between opaque and transparent modes. The switching principle is that in the presence of Joule-heat, solid paraffin would be melt and swell within 20 s to enable a slippery surface for decreasing light scattering and frictional force derived from contact angle hysteresis (F_CAH ). Once Joule-heat is discharged, undulating rough surface would reconfigure by cold-shrinkage of paraffin within 8 s to render light blockage and high F_CAH . Upon its portable merit, in situ thermal management, programmable visibility, as well as steering functionalized droplets by electric-activated JR-PISSs are successfully deployed. Compared with previous Nepenthes-inspired slippery surfaces, the current JR-PISS is more competent for in situ harnessing optical and wetting properties on-demand.

SUBMITTER: Chen C

PROVIDER: S-EPMC8292917 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Laser-textured surfaces enabling reversible wettability switching and improved optical properties are gaining importance in cutting-edge applications, including self-cleaning interfaces, tunable optical lenses, microfluidics, and lab-on-chip systems. Fabrication of such surfaces by combining nanosecond-laser texturing and low-temperature annealing of titanium Ti-6Al-4V alloy was demonstrated by Lian et al. in ACS Appl. Mater. Inter. 2020, 12 (5), 6573-6580. However, it is difficult to agree with (i) their contradictory explanation of the wettability transition due to low-temperature annealing and (ii) their theoretical description of the optical behavior of the laser-textured titanium surface. This comment provides an alternative view-supported by both experimental results and theoretical investigation-on how the results by Lian et al. could be interpreted more correctly. The annealing experiments clarify that controlled contamination is crucial in obtaining consistent surface wettability alterations after low-temperature annealing. Annealing of laser-textured titanium at 100 °C in contaminated and contaminant-free furnaces leads to completely different wettability transitions. Analysis of the surface chemistry by XPS and ToF-SIMS reveals that (usually overlooked) contamination with hydrophobic polydimethylsiloxane (PDMS) may arise from the silicone components of the furnace. In this case, a homogeneous thin PDMS film over the entire surface results in water repellency (contact angle of 161° and roll-off angle of 15°). In contrast, annealing under the same conditions but in a contaminant-free furnace preserves the initial superhydrophilicity, whereas the annealing at 350 °C turns the hydrophobicity "off". The theoretical calculations of optical properties demonstrate that the laser-induced oxide layer formed during the laser texturing significantly influences the surface optical behavior. Consequently, the interference of light reflected by the air-oxide and the oxide-metal interfaces should not be neglected and enables several advanced approaches to exploit such optical properties.

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In Situ Electric-Induced Switchable Transparency and Wettability on Laser-Ablated Bioinspired Paraffin-Impregnated Slippery Surfaces.

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