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Six-membered-ring inorganic materials: definition and prospects.


ABSTRACT: The six-membered ring (SMR) is a common structure unit for numerous material systems. These materials include, but are not limited to, the typical two-dimensional materials such as graphene, h-BN, and transition metal dichalcogenides, as well as three-dimensional materials such as beryllium, magnesium, MgB2 and Bi2Se3. Although many of these materials have already become 'stars' in materials science and condensed-matter physics, little attention has been paid to the roles of the SMR unit across a wide range of compositions and structures. In this article, we systematically analyze these materials with respect to their very basic SMR structural unit, which has been found to play a deterministic role in the occurrence of many intriguing properties and phenomena, such as Dirac electronic and phononic spectra, superconductivity and topology. As a result, we have defined this group of materials as SMR inorganic materials, opening up a new perspective on materials research and development. With their unique properties, SMR materials deserve wide attention and in-depth investigation from materials design, new physical discoveries to target-wizard applications. It is expected that SMR materials will find niche applications in next-generation information technology, renewable energy, space, etc.

SUBMITTER: Liu G 

PROVIDER: S-EPMC8294346 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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Six-membered-ring inorganic materials: definition and prospects.

Liu Gang G   Chen Xing-Qiu XQ   Liu Bilu B   Ren Wencai W   Cheng Hui-Ming HM  

National science review 20200928 1


The six-membered ring (SMR) is a common structure unit for numerous material systems. These materials include, but are not limited to, the typical two-dimensional materials such as graphene, <i>h</i>-BN, and transition metal dichalcogenides, as well as three-dimensional materials such as beryllium, magnesium, MgB<sub>2</sub> and Bi<sub>2</sub>Se<sub>3</sub>. Although many of these materials have already become 'stars' in materials science and condensed-matter physics, little attention has been p  ...[more]

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