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Cerium-photocatalyzed aerobic oxidation of benzylic alcohols to aldehydes and ketones.

ABSTRACT: We have developed a cerium-photocatalyzed aerobic oxidation of primary and secondary benzylic alcohols to aldehydes and ketones using inexpensive CeCl₃·7H₂O as photocatalyst and air oxygen as the terminal oxidant.

SUBMITTER: Yedase GS

PROVIDER: S-EPMC8313980 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature

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Cerium-photocatalyzed aerobic oxidation of benzylic alcohols to aldehydes and ketones.

Yedase Girish Suresh GS Kumar Sumit S Stahl Jessica J König Burkhard B Yatham Veera Reddy VR

Beilstein journal of organic chemistry 20210723

We have developed a cerium-photocatalyzed aerobic oxidation of primary and secondary benzylic alcohols to aldehydes and ketones using inexpensive CeCl<sub>3</sub>·7H<sub>2</sub>O as photocatalyst and air oxygen as the terminal oxidant. ...[more]

PMID: 34367351

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