Optimization and Characterization of Polyphosphate Fertilizers by Two Different Manufacturing Processes.
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ABSTRACT: To explore how different reaction parameters affect the major features of short-chain ammonium polyphosphate (APP) fertilizers, a batch of manufacturing experiments were conducted under two different manufacturing processes [phosphoric acid (PA)-urea and monoammonium phosphate (MAP)-urea]. The APP features including polymerization degree, polymerization rate, solubility, and N and P recovery rates were significantly varied and influenced by the molar ratio of raw materials (P:N), reaction temperature, time, and pressure under different manufacturing conditions. In the MAP-urea process, the optimized APP products were gained under the combination condition of molar ratio = 1.6:1, T = 130 °C, and t = 45 min, while this happened in molar ratio = 1:1.7, T = 180 °C, and t = 60 min in the PA-urea process. Comprehensively, the features of APP fertilizers produced by the MAP-urea process were better than those produced by the PA-urea process. Our results provide valuable references for manufacturing high-quality short-chain APP fertilizers.
SUBMITTER: Wang X
PROVIDER: S-EPMC8320069 | biostudies-literature |
REPOSITORIES: biostudies-literature
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