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The Provenance of Slovenian Milk Using ⁸⁷Sr/⁸⁶Sr Isotope Ratios.

ABSTRACT: This work presents the first use of Sr isotope ratios for determining the provenance of bovine milk from different regions of Slovenia. The analytical protocol for the determination of ⁸⁷Sr/⁸⁶Sr isotope ratio was optimised and applied to authentic milk samples. Considerable variability of ⁸⁷Sr/⁸⁶Sr ratios found in Slovenian milk reflects the substantial heterogeneity of the geological background of its origin. The results, although promising, cannot discount possible inter-annual or annual variation of the Sr isotopic composition of milk. The ⁸⁷Sr/⁸⁶Sr ratios of groundwater and surface waters are in good correlation with milk, indicating that the Sr isotopic fingerprint in milk is reflective of cow drinking water. The ⁸⁷Sr/⁸⁶Sr ratio has the potential to distinguish between different milk production areas as long as these areas are characterised by geo-lithology. Discriminant analysis (DA) incorporating the elemental composition and stable isotopes of light elements showed that ⁸⁷Sr/⁸⁶Sr ratio together with δ¹³C_cas and δ¹⁵N_cas values have the main discrimination power to distinguish the Quaternary group (group 6) from the others. Group 1 (Cretaceous: Carbonate Rocks and Flysch) is associated with Br content, 1/Sr and δ¹⁸O_w values. The overall prediction ability was found to be 63.5%. Pairwise comparisons using OPLS-DA confirmed that diet and geologic parameters are important for the separation.

SUBMITTER: Gregorcic SH

PROVIDER: S-EPMC8393216 | biostudies-literature |

REPOSITORIES: biostudies-literature

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