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Direct One-Step Growth of Bimetallic Ni2Mo3N on Ni Foam as an Efficient Oxygen Evolution Electrocatalyst.


ABSTRACT: A simple and economical synthetic route for direct one-step growth of bimetallic Ni2Mo3N nanoparticles on Ni foam substrate (Ni2Mo3N/NF) and its catalytic performance during an oxygen evolution reaction (OER) are reported. The Ni2Mo3N/NF catalyst was obtained by annealing a mixture of a Mo precursor, Ni foam, and urea at 600 °C under N2 flow using one-pot synthesis. Moreover, the Ni2Mo3N/NF exhibited high OER activity with low overpotential values (336.38 mV at 50 mA cm-2 and 392.49 mV at 100 mA cm-2) and good stability for 5 h in Fe-purified alkaline electrolyte. The Ni2Mo3N nanoparticle surfaces converted into amorphous surface oxide species during the OER, which might be attributed to the OER activity.

SUBMITTER: Park SH 

PROVIDER: S-EPMC8398334 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

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Direct One-Step Growth of Bimetallic Ni<sub>2</sub>Mo<sub>3</sub>N on Ni Foam as an Efficient Oxygen Evolution Electrocatalyst.

Park Sang Heon SH   Kang Soon Hyung SH   Youn Duck Hyun DH  

Materials (Basel, Switzerland) 20210823 16


A simple and economical synthetic route for direct one-step growth of bimetallic Ni<sub>2</sub>Mo<sub>3</sub>N nanoparticles on Ni foam substrate (Ni<sub>2</sub>Mo<sub>3</sub>N/NF) and its catalytic performance during an oxygen evolution reaction (OER) are reported. The Ni<sub>2</sub>Mo<sub>3</sub>N/NF catalyst was obtained by annealing a mixture of a Mo precursor, Ni foam, and urea at 600 °C under N<sub>2</sub> flow using one-pot synthesis. Moreover, the Ni<sub>2</sub>Mo<sub>3</sub>N/NF exhibit  ...[more]

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