Ontology highlight
ABSTRACT:
SUBMITTER: Guo HM
PROVIDER: S-EPMC8433232 | biostudies-literature | 2021 Sep
REPOSITORIES: biostudies-literature
Nature communications 20210910 1
The delivery of alkyl radicals through photocatalytic deoxygenation of primary alcohols under mild conditions is a so far unmet challenge. In this report, we present a one-pot strategy for deoxygenative Giese reaction of alcohols with electron-deficient alkenes, by using xanthate salts as alcohol-activating groups for radical generation under visible-light photoredox conditions in the presence of triphenylphosphine. The convenient generation of xanthate salts and high reactivity of sequential C- ...[more]