Ontology highlight
ABSTRACT:
SUBMITTER: Friese FW
PROVIDER: S-EPMC6772128 | biostudies-literature | 2019 Jul
REPOSITORIES: biostudies-literature
Friese Florian W FW Studer Armido A
Angewandte Chemie (International ed. in English) 20190605 28
Two different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal-free silyl-radical-mediated pathway or utilize visible-light photoredox catalysis. Readily available xanthates or methyl oxalates are used as radical precursors. The reactions show broad substrate scope and high functional-group tolerance, and are conducted under mild and practical conditions. ...[more]