Unknown

Dataset Information

0

Deoxygenative Borylation of Secondary and Tertiary Alcohols.


ABSTRACT: Two different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal-free silyl-radical-mediated pathway or utilize visible-light photoredox catalysis. Readily available xanthates or methyl oxalates are used as radical precursors. The reactions show broad substrate scope and high functional-group tolerance, and are conducted under mild and practical conditions.

SUBMITTER: Friese FW 

PROVIDER: S-EPMC6772128 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

altmetric image

Publications

Deoxygenative Borylation of Secondary and Tertiary Alcohols.

Friese Florian W FW   Studer Armido A  

Angewandte Chemie (International ed. in English) 20190605 28


Two different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal-free silyl-radical-mediated pathway or utilize visible-light photoredox catalysis. Readily available xanthates or methyl oxalates are used as radical precursors. The reactions show broad substrate scope and high functional-group tolerance, and are conducted under mild and practical conditions. ...[more]

Similar Datasets

| S-EPMC8370987 | biostudies-literature
| S-EPMC8643278 | biostudies-literature
| S-EPMC7801780 | biostudies-literature
| S-EPMC8433232 | biostudies-literature
| S-EPMC4804746 | biostudies-literature
| S-EPMC6707304 | biostudies-literature
| S-EPMC6583784 | biostudies-literature
| S-EPMC5814735 | biostudies-literature
| S-EPMC3028934 | biostudies-literature
| S-EPMC3982934 | biostudies-literature