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MOF-Derived ZnS Nanodots/Ti₃C₂T_x MXene Hybrids Boosting Superior Lithium Storage Performance.

ABSTRACT: ZnS has great potentials as an anode for lithium storage because of its high theoretical capacity and resource abundance; however, the large volume expansion accompanied with structural collapse and low conductivity of ZnS cause severe capacity fading and inferior rate capability during lithium storage. Herein, 0D-2D ZnS nanodots/Ti₃C₂T_x MXene hybrids are prepared by anchoring ZnS nanodots on Ti₃C₂T_x MXene nanosheets through coordination modulation between MXene and MOF precursor (ZIF-8) followed with sulfidation. The MXene substrate coupled with the ZnS nanodots can synergistically accommodate volume variation of ZnS over charge-discharge to realize stable cyclability. As revealed by XPS characterizations and DFT calculations, the strong interfacial interaction between ZnS nanodots and MXene nanosheets can boost fast electron/lithium-ion transfer to achieve excellent electrochemical activity and kinetics for lithium storage. Thereby, the as-prepared ZnS nanodots/MXene hybrid exhibits a high capacity of 726.8 mAh g^-1 at 30 mA g^-1, superior cyclic stability (462.8 mAh g^-1 after 1000 cycles at 0.5 A g^-1), and excellent rate performance. The present results provide new insights into the understanding of the lithium storage mechanism of ZnS and the revealing of the effects of interfacial interaction on lithium storage performance enhancement.

SUBMITTER: Cao B

PROVIDER: S-EPMC8473522 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:The pursuit of new and better battery materials has given rise to numerous studies of the possibilities to use two-dimensional negative electrode materials, such as MXenes, in lithium-ion batteries. Nevertheless, both the origin of the capacity and the reasons for significant variations in the capacity seen for different MXene electrodes still remain unclear, even for the most studied MXene: Ti3C2 T x . Herein, freestanding Ti3C2 T x MXene films, composed only of Ti3C2 T x MXene flakes, are studied as additive-free negative lithium-ion battery electrodes, employing lithium metal half-cells and a combination of chronopotentiometry, cyclic voltammetry, X-ray photoelectron spectroscopy, hard X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy experiments. The aim of this study is to identify the redox reactions responsible for the observed reversible and irreversible capacities of Ti3C2 T x -based lithium-ion batteries as well as the reasons for the significant capacity variation seen in the literature. The results demonstrate that the reversible capacity mainly stems from redox reactions involving the T x -Ti-C titanium species situated on the surfaces of the MXene flakes, whereas the Ti-C titanium present in the core of the flakes remains electro-inactive. While a relatively low reversible capacity is obtained for electrodes composed of pristine Ti3C2 T x MXene flakes, significantly higher capacities are seen after having exposed the flakes to water and air prior to the manufacturing of the electrodes. This is ascribed to a change in the titanium oxidation state at the surfaces of the MXene flakes, resulting in increased concentrations of Ti(II), Ti(III), and Ti(IV) in the T x -Ti-C surface species. The significant irreversible capacity seen in the first cycles is mainly attributed to the presence of residual water in the Ti3C2 T x electrodes. As the capacities of Ti3C2 T x MXene negative electrodes depend on the concentration of Ti(II), Ti(III), and Ti(IV) in the T x -Ti-C surface species and the water content, different capacities can be expected when using different manufacturing, pretreatment, and drying procedures.

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MOF-Derived ZnS Nanodots/Ti₃C₂T_x MXene Hybrids Boosting Superior Lithium Storage Performance.

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OmicsDI is part of the ELIXIR infrastructure

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MOF-Derived ZnS Nanodots/Ti3C2Tx MXene Hybrids Boosting Superior Lithium Storage Performance.

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OmicsDI is part of the ELIXIR infrastructure

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MOF-Derived ZnS Nanodots/Ti₃C₂T_x MXene Hybrids Boosting Superior Lithium Storage Performance.