Dataset Information

G-C₃N₄/Ca₂Fe₂O₅ heterostructures for enhanced photocatalytic degradation of organic effluents under sunlight.

ABSTRACT: g-C₃N₄/Ca₂Fe₂O₅ heterostructures were successfully prepared by incorporating g-C₃N₄ into Ca₂Fe₂O₅ (CFO). As prepared g-C₃N₄/CFO heterostructures were initially utilized to photodegrade organic effluent Methylene blue (MB) for optimization of photodegradation performance. 50% g-C₃N₄ content in CFO composition showed an enhanced photodegradation efficiency (~ 96%) over g-C₃N₄ (48.15%) and CFO (81.9%) due to mitigation of recombination of photogenerated charge carriers by Type-II heterojunction. The optimized composition of heterostructure was further tested for degradation of Bisphenol-A (BPA) under direct sunlight, exhibiting enhanced photodegradation efficiency of about 63.1% over g-C₃N₄ (17%) and CFO (45.1%). The photoelectrochemical studies at various potentials with and without light illumination showed significant improvement in photocurrent response for g-C₃N₄/Ca₂Fe₂O₅ heterostructures (~ 1.9 mA) over CFO (~ 67.4 μA). These studies revealed efficient solar energy harvesting ability of g-C₃N₄/Ca₂Fe₂O₅ heterostructures to be utilized for organic effluent treatment.

SUBMITTER: Vavilapalli DS

PROVIDER: S-EPMC8490349 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:We have synthesized MoS2 incorporated α-Fe2O3/ZnO nanocomposites by adapting a facile hydrothermal synthesis process. The effect of incorporating ultrasonically exfoliated few-layer MoS2 nanosheets on the solar-light driven photocatalytic performance of α-Fe2O3/ZnO photocatalyst nanocomposites has been demonstrated. Structural, morphological and optical characteristics of the as-synthesized nanomaterials are comprehensively investigated and analyzed by performing Rietveld refinement of powder X-ray diffraction patterns, field emission scanning electron microscopy and UV-visible spectroscopy, respectively. The photoluminescence spectra of the as-prepared nanocomposites elucidate that the recombination of photogenerated electron-hole pairs is highly suppressed due to incorporation of MoS2 nanosheets. Notably, the ultrasonicated MoS2 incorporated α-Fe2O3/ZnO nanocomposite manifests 91% and 83% efficiency in degradation of rhodamine B dye and antibiotic ciprofloxacin respectively under solar illumination. Active species trapping experiments reveal that the hydroxyl (˙OH) radicals play a significant role in RhB degradation. Likewise the dye degradation efficiency, the amount of hydrogen produced by this nanocomposite via photocatalytic water splitting is also considerably higher as compared to both non-ultrasonicated MoS2 incorporated α-Fe2O3/ZnO and α-Fe2O3/ZnO nanocomposites as well as Degussa P25 titania nanoparticles. This indicates the promising potential of the incorporation of ultrasonicated MoS2 with α-Fe2O3/ZnO nanocomposites for the generation of carbon-free hydrogen by water splitting. The substantial increase in the photocatalytic efficiency of α-Fe2O3/ZnO after incorporation of ultrasonicated MoS2 can be attributed to its favorable band structure, large surface to volume ratio, effective segregation and migration of photogenerated electron-hole pairs at the interface of heterojunctions and the plethora of exposed active edge sites provided by the few-layer MoS2 nanosheets.

Dataset Information

G-C₃N₄/Ca₂Fe₂O₅ heterostructures for enhanced photocatalytic degradation of organic effluents under sunlight.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

G-C3N4/Ca2Fe2O5 heterostructures for enhanced photocatalytic degradation of organic effluents under sunlight.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets

G-C₃N₄/Ca₂Fe₂O₅ heterostructures for enhanced photocatalytic degradation of organic effluents under sunlight.