Unknown

Dataset Information

0

Nickel-Catalyzed Kumada Cross-Coupling Reactions of Benzylic Sulfonamides.

ABSTRACT: Herein, we report a Kumada cross-coupling reaction of benzylic sulfonamides. The scope of the transformation includes acyclic and cyclic sulfonamide precursors that cleanly produce highly substituted acyclic fragments. Preliminary data are consistent with a stereospecific mechanism that allows for a diastereoselective reaction.

SUBMITTER: Hewitt KA 

PROVIDER: S-EPMC8512530 | biostudies-literature |

REPOSITORIES: biostudies-literature

Json Xml

Similar Datasets

Unknown Nickel-catalyzed Kumada cross-coupling reactions of tertiary alkylmagnesium halides and aryl bromides/triflates.
| S-EPMC8036247 | biostudies-literature
Unknown Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates.
| S-EPMC5539537 | biostudies-literature
Unknown Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers with Isotopically-Labeled Grignard Reagents.
| S-EPMC4955521 | biostudies-literature
Unknown Identification of the Active Catalyst for Nickel-Catalyzed Stereospecific Kumada Coupling Reactions of Ethers.
| S-EPMC7872209 | biostudies-literature
Unknown A Unified Explanation for Chemoselectivity and Stereospecificity of Ni-Catalyzed Kumada and Cross-Electrophile Coupling Reactions of Benzylic Ethers: A Combined Computational and Experimental Study.
| S-EPMC6773265 | biostudies-literature
Unknown Nickel/bis(oxazoline)-catalyzed asymmetric Kumada reactions of alkyl electrophiles: cross-couplings of racemic alpha-bromoketones.
| S-EPMC2814537 | biostudies-literature
Unknown Nickel-catalyzed Negishi cross-coupling reactions of secondary alkylzinc halides and aryl iodides.
| S-EPMC6474776 | biostudies-literature
Unknown Photochemical Asymmetric Nickel-Catalyzed Acyl Cross-Coupling.
| S-EPMC6900114 | biostudies-literature
Unknown Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex.
| S-EPMC7075318 | biostudies-literature
Unknown Nickel-catalyzed migratory alkyl-alkyl cross-coupling reaction.
| S-EPMC8162388 | biostudies-literature