Ontology highlight
ABSTRACT:
SUBMITTER: An Y
PROVIDER: S-EPMC8513894 | biostudies-literature | 2021 Oct
REPOSITORIES: biostudies-literature
Chemical science 20210831 39
This report describes palladium-catalyzed C-H glycosylation and retro Diels-Alder tandem reaction <i>via</i> structurally modified norbornadienes (smNBDs). smNBDs were proposed to regulate the reactivity of the aryl-norbornadiene-palladacycle (ANP), including its high chemoselectivity and regioselectivity, which were the key to constructing C2 and C3 unsubstituted C4-glycosidic indoles. The scope of this substrate is extensive; the halogenated six-membered and five-membered glycosides were appli ...[more]