Browse
Submit Data
Databases
API
Help

Dataset Information

25 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Weaving host matrices with intermolecular hydrogen bonds for high-efficiency white thermally activated delayed fluorescence.

ABSTRACT: A thermally activated delayed fluorescence (TADF) white organic light-emitting diode (WOLED) holds great promise for low-cost, large-scale lighting applications. Nevertheless, manipulating exciton allocation in a white TADF single layer is still a challenge. Herein, we demonstrate that the exciton kinetic process of dually doped white TADF films is strongly dependent on the grid regularity of the host matrix. Intermolecular hydrogen bonds (IHBs) are used to weave the matrices of two host molecules DPEQPO and DPSQPO featuring four phosphine oxide (PO) groups and different IHB orientations. The DPSQPO matrix forms regular grids to uniformly disperse and separate dopants, while DPEQPO exhibits chaotic IHBs, in turn inducing a heterogeneous dopant distribution. As a consequence, in both photoluminescence and electroluminescence processes, in contrast to DPEQPO hosted systems with comparable singlet Förster resonance energy transfer and triplet Dexter energy transfer, DPSQPO provides a FRET-predominant exciton allocation between blue and yellow dopants, which markedly suppresses triplet quenching and improves the white color purity, resulting in a state-of-the-art external quantum efficiency up to 24.2% of its single-emissive-layer pure-white TADF diode, in contrast to 16.0% for DPEQPO based analogs. These results indicate the significance of host engineering for exciton kinetics and suggest the feasibility of host grid design for developing high-performance TADF lighting.

SUBMITTER: Tian Y

PROVIDER: S-EPMC8580069 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Exciplex energy transfer through spacer: White electroluminescence with enhanced stability based on cyan intermolecular and orange intramolecular thermally activated delayed fluorescence.

Project description:Capability of exciplex energy transfer through a spacer was investigated using three exciplex-forming solid mixtures which contained the well-known electron accepting 2,4,6-tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine and appropriately designed bipolar cyanocarbazolyl-based derivatives functionalized by attachment of carbazolyl, acridanyl or phenyl units. These novel cyanocarbazolyl-based derivatives were used as both the spacer and exciplex-forming donor. Efficient organic light-emitting diodes with electroluminescence in cyan-yellow region and maximum external quantum efficiency of up to 7.7% were fabricated owing to efficient thermally activated fluorescence (TADF) of the newly discovered exciplexes. An approach of exciton separation by the spacer between the studied exciplexes and selected orange TADF emitter was proposed for the fabrication of white electroluminescent devices with prolonged lifetime comparing to that of single-color exciplex-based devices. Exciplex-forming systems were tested for exciton separation between inter- and intramolecular TADF. Exciplex energy transfer through a spacer was observed on relatively long distance for one system due to the energy resonance between triplet levels of the exciplex and spacer. First time observed here exciplex energy transfer through a spacer can be useful for both improvement of device stability and obtaining of white electroluminescence.

| S-EPMC7248288 | biostudies-literature

High-Efficiency Diphenylpyrimidine Derivatives Blue Thermally Activated Delayed Fluorescence Organic Light-Emitting Diodes.

Project description:Organic light-emitting diodes with thermally activated delayed fluorescence emitter have been developed with highly twisted donor-acceptor configurations and color-pure blue emitters. Synthesized 4-(4-(4,6-diphenylpyrimidin-2-yl)phenyl)-10H-spiro[acridine-9,9'-fluorene] (4,6-PhPMAF) doped device with spiroacridine as a donor unit and diphenylpyrimidine as acceptor exhibits the device characteristics such as the luminescence, external quantum efficiencies, current efficiencies, and power efficiencies corresponding to 213 cd/m2, 2.95%, 3.27 cd/A, and 2.94 lm/W with Commission International de l'Eclairage (CIE) coordinates of (0.15, 0.11) in 4,6-PhPMAF-doped DPEPO emitter. The reported 10-(4-(2,6-diphenylpyrimidin-4-yl)phenyl)-10H-spiro[acridine-9,9'-fluorene] (2,6-PhPMAF) doped device exhibit high device performance with 1,445 cd/m2, 12.38%, 19.6 cd/A, and 15.4 lm/W, which might be originated from increased internal quantum efficiency by up-converted triplet excitons to the singlet state with relatively smaller ?E ST of 0.17 eV and higher reverse intersystem crossing rate (k RISC) of 1.0 ×108/s in 2,6-PhPMAF than 0.27 eV and 3.9 ×107/s in 4,6-PhPMAF. Despite low performance of 4,6-PhPMAF doped device, synthesized 4,6-PhPMAF has better color purity as a deep-blue emission with y axis (0.11) than reported 2,6-PhPMAF with y axis (0.19) in CIE coordinate. The synthesized 4,6-PhPMAF has higher thermal stability of any transition up to 300°C and decomposition temperature with only 5% weight loss in 400°C than reported 2,6-PhPMAF. The maximum photoluminescence emission of 4,6-PhPMAF in various solvents appeared at 438 nm, which has blue shift about 20 nm than that of 2,6-PhPMAF, which contributes deep-blue emission in synthesized 4,6-PhPMAF.

| S-EPMC7240071 | biostudies-literature

A Novel Design Strategy for Suppressing Efficiency Roll-Off of Blue Thermally Activated Delayed Fluorescence Molecules through Donor-Acceptor Interlocking by C-C Bonds.

Project description:The short material lifetime of thermally activated delayed fluorescence (TADF) technology is a major obstacle to the development of economically feasible, highly efficient, and durable devices for commercial applications. TADF devices are also hampered by insufficient operational stability. In this paper, we report the design, synthesis, and evaluation of new TADF molecules possessing a sterically twisted skeleton by interlocking donor and acceptor moieties through a C-C bond. Compared to C-N-bond TADF molecules, such as CPT2, the C-C-bond TADF molecules showed a large dihedral angle increase by more than 30 times and a singlet-triplet energy-gap decrease to less than 0.22 eV because of the steric hindrance caused by the direct C-C bond connection. With the introduction of a dibenzofuran core structure, devices comprising BMK-T317 and BMK-T318 exhibited a magnificent display performance, especially their external quantum efficiencies, which were as high as 19.9% and 18.8%, respectively. Moreover, the efficiency roll-off of BMK-T318 improved significantly (26.7%). These results indicate that stability of the material can be expected through the reduction of their singlet-triplet splitting and the precise adjustment of dihedral angles between the donor-acceptor skeletons.

| S-EPMC6956325 | biostudies-literature

Long-lived spin-polarized intermolecular exciplex states in thermally activated delayed fluorescence-based organic light-emitting diodes.

Project description:[Figure: see text].

| S-EPMC8598001 | biostudies-literature

Trap-Controlled White Electroluminescence From a Single Red-Emitting Thermally Activated Delayed Fluorescence Polymer.

Project description:Single white-emitting polymers have been reported by incorporating the second-generation carbazole dendron into the side chain of a red-emitting thermally activated delayed fluorescence (TADF) polymer. Due to the prevented hole trap effect, in this case, excitons can be generated simultaneously on the polymeric host and the red TADF dopant to give a dual emission. Consequently, a bright white electroluminescence is achieved even at a dopant loading as high as 5 mol.%, revealing a maximum luminous efficiency of 16.1 cd/A (12.0 lm/W, 8.2%) and Commission Internationale de l'Eclairage (CIE) coordinates of (0.42, 0.32). The results clearly indicate that the delicate tuning of charge trap is a promising strategy to develop efficient single white-emitting polymers, whose low-band-gap chromophore content can be up to a centesimal level.

| S-EPMC7186499 | biostudies-literature

Intramolecular Hydrogen Bonding in Thermally Activated Delayed Fluorescence Emitters: Is There Evidence Beyond Reasonable Doubt?

Project description:Intramolecular hydrogen bonding between donor and acceptor segments in thermally activated delayed fluorescence (TADF) materials is now frequently employed to─purportedly─rigidify the structure and improve the emission performance of these materials. However, direct evidence for these intramolecular interactions is often lacking or ambiguous, leading to assertions that are largely speculative. Here we investigate a series of TADF-active materials incorporating pyridine, which bestows the potential ability to form intramolecular H-bonding interactions. Despite possible indications of H-bonding from an X-ray analysis, an array of other experimental investigations proved largely inconclusive. Instead, after examining computational potential energy surfaces of the donor-acceptor torsion angle we conclude that the pyridine group primarily alleviates steric congestion in our case, rather than enabling an H-bond interaction as elsewhere assumed. We suggest that many previously reported "H-bonding" TADF materials featuring similar chemical motifs may instead operate similarly and that investigation of potential energy surfaces should become a key feature of future studies.

| S-EPMC9465681 | biostudies-literature

Optimizing the Intralayer and Interlayer Compatibility for High-Efficiency Blue Thermally Activated Delayed Fluorescence Diodes.

Project description:A series of phosphine oxide hosts, 4,6-bis(diphenylphosphoryl) dibenzothiophene (DBTDPO) and 4- diphenylphosphoryldibenzothiophene (DBTSPO), and electron transporting materials (ETM), 2-(diphenylphosphoryl)dibenzothiophene sulfone (2DBSOSPO), 3-(diphenylphosphoryl)dibenzothiophene sulfone (3DBSOSPO) and 4-(diphenylphosphoryl)dibenzothiophene sulfone (4DBSOSPO) were developed to support blue thermally activated delayed fluorescence (TADF) devices with high performance through optimizing intralayer and interlayer compatibility of emissive layers. On the basis of the triplet energy of ~3.0?eV for the hosts and ETMs, excitons can be effectively confined on DMAC-DPS. Compared to DBTSPO, DBTDPO can support the excellent distribution uniformity to blue TADF dye bis[4-(9,9-dimethyl-9,10-dihydroacridine) phenyl] sulfone (DMAC-DPS), owing to their configuration similarity; while 3DBSOSPO and 4DBSOSPO are superior in compatibility with the hosts due to the similar molecular polarity or configuration. Through adjusting the molecular configuration, the electrical performance of ETMs can be feasibly tuned, including the excellent electron mobility (?e) by the order of 10(-3)?cm(2)?V(-1)?s(-1). As the result, DBTDPO and 4DBSOSPO endowed their four-layer blue TADF devices with the maximum current efficiency of 33.5?cd A(-1) and the maximum external quantum efficiency more than 17%, which are impressive among the best blue TADF devices. It is showed that intralayer compatibility determines the maximum efficiencies, while interlayer compatibility influences efficiency stability.

| S-EPMC4731786 | biostudies-literature

Thermally activated delayed fluorescence with 7% external quantum efficiency from a light-emitting electrochemical cell.

Project description:We report on light-emitting electrochemical cells, comprising a solution-processed single-layer active material and air-stabile electrodes, that exhibit efficient and bright thermally activated delayed fluorescence. Our optimized devices delivers a luminance of 120 cd m-2 at an external quantum efficiency of 7.0%. As such, it outperforms the combined luminance/efficiency state-of-the art for thermally activated delayed fluorescence light-emitting electrochemical cells by one order of magnitude. For this end, we employed a polymeric blend host for balanced electrochemical doping and electronic transport as well as uniform film formation, an optimized concentration (<1 mass%) of guest for complete host-to-guest energy transfer at minimized aggregation and efficient emission, and an appropriate concentration of an electrochemically stabile electrolyte for desired doping effects. The generic nature of our approach is manifested in the attainment of bright and efficient thermally activated delayed fluorescence emission from three different light-emitting electrochemical cells with invariant host:guest:electrolyte number ratio.

| S-EPMC6874610 | biostudies-literature

Constructing high-efficiency orange-red thermally activated delayed fluorescence emitters by three-dimension molecular engineering.

Project description:Preparing high-efficiency solution-processable orange-red thermally activated delayed fluorescence (TADF) emitters remains challenging. Herein, we design a series of emitters consisting of trinaphtho[3,3,3]propellane (TNP) core derivatized with different TADF units. Benefiting from the unique hexagonal stacking architecture of TNPs, TADF units are thus kept in the cavities between two TNPs, which decrease concentration quenching and annihilation of long-lived triplet excitons. According to the molecular engineering of TADF and host units, the excited states can further be regulated to effectively enhance spin-orbit coupling (SOC) processes. We observe a high-efficiency orange-red emission at 604 nm in one instance with high SOC value of 0.862 cm-1 and high photoluminescence quantum yield of 70.9%. Solution-processable organic light-emitting diodes exhibit a maximum external quantum efficiency of 24.74%. This study provides a universal strategy for designing high-performance TADF emitters through molecular packing and excited state regulation.

| S-EPMC9763412 | biostudies-literature

Benzoate-based thermally activated delayed fluorescence materials.

Project description:Compounds PTZ-MBZ (methyl 3-(10H-phenothiazin-10-yl)benzoate) and DMAC-MBZ (methyl 3-(9,9-dimethylacridin-10(9H)-yl)benzoate) were conveniently synthesized, and they exhibited TADF properties with lifetimes of 0.80 and 2.17 μs, respectively. The spatially separated highest occupied molecular orbital and lowest unoccupied molecular orbital resulted in a very small singlet-triplet energy gap of 0.0152 eV and 0.0640 eV, respectively. Thermally activated delayed fluorescence materials with short lifetime could be used as promising luminescent materials for organic light-emitting diodes.

| S-EPMC10346356 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data